Product Name

  • Name

    1 -(Ethenyloxy)-butane

  • EINECS 203-860-7
  • CAS No. 111-34-2
  • Article Data48
  • CAS DataBase
  • Density 0.776 g/cm3
  • Solubility 3 g/L (20 °C) in water
  • Melting Point -92 °C(lit.)
  • Formula C6H12O
  • Boiling Point 93.6 °C at 760 mmHg
  • Molecular Weight 100.161
  • Flash Point 15°F
  • Transport Information UN 2352 3/PG 2
  • Appearance clear liquid
  • Safety 9-14-16-33
  • Risk Codes 11-19
  • Molecular Structure Molecular Structure of 111-34-2 (1 -(Ethenyloxy)-butane)
  • Hazard Symbols FlammableF
  • Synonyms n-Butyl vinyl ether;Ether,butyl vinyl (8CI);1-(Ethenyloxy)butane;1-(Vinyloxy)butane;1-Butoxyethene;BVE;Butoxyethene;Butoxyethylene;Butane, 1-(ethenyloxy)-;NBVE;NSC 8264;Vinylbutyl ether;Vinyl n-butyl ether;
  • PSA 9.23000
  • LogP 1.94660

Synthetic route

dibutyl acetal
871-22-7

dibutyl acetal

6,6-Dimethyloenanthsaeure
15898-92-7

6,6-Dimethyloenanthsaeure

-butyl vinyl ether
111-34-2

-butyl vinyl ether

Conditions
ConditionsYield
83%
acetylene
74-86-2

acetylene

butan-1-ol
71-36-3

butan-1-ol

-butyl vinyl ether
111-34-2

-butyl vinyl ether

Conditions
ConditionsYield
With sodium hydroxide; cesium fluoride at 135 - 140℃; under 7600 - 10640 Torr; for 3h;82%
With sodium butanolate at 100 - 150℃;
With potassium n-butoxide; paraffin oil at 180 - 190℃;
(2-butoxy-ethanesulfinyl)-ethene
81577-06-2

(2-butoxy-ethanesulfinyl)-ethene

A

-butyl vinyl ether
111-34-2

-butyl vinyl ether

B

ethenesulfenic acid
2492-74-2

ethenesulfenic acid

Conditions
ConditionsYield
With potassium hydroxide at 280 - 290℃;A 68%
B n/a
vinyltriethylsilane
1112-54-5

vinyltriethylsilane

butan-1-ol
71-36-3

butan-1-ol

A

-butyl vinyl ether
111-34-2

-butyl vinyl ether

B

hexaethyl disiloxane
994-49-0

hexaethyl disiloxane

Conditions
ConditionsYield
With bromine for 4h;A 65%
B 20%
dibutyl acetal
871-22-7

dibutyl acetal

A

-butyl vinyl ether
111-34-2

-butyl vinyl ether

B

butan-1-ol
71-36-3

butan-1-ol

Conditions
ConditionsYield
phosphoric acid at 200℃; Product distribution; various catalysts;A 12.5%
B 16.7%
butane, 1-(1-ethoxyethoxy)-
57006-87-8

butane, 1-(1-ethoxyethoxy)-

-butyl vinyl ether
111-34-2

-butyl vinyl ether

Conditions
ConditionsYield
at 300℃; beim Leiten ueber Kaolin;
dibutyl acetal
871-22-7

dibutyl acetal

-butyl vinyl ether
111-34-2

-butyl vinyl ether

Conditions
ConditionsYield
With sodium hydrogen sulfate
With phosphoric acid
With palladium asbestos at 300℃;
With boric acid asbestos at 380 - 410℃;
1,1-dibutoxy-2-chloro-ethane
17437-27-3

1,1-dibutoxy-2-chloro-ethane

-butyl vinyl ether
111-34-2

-butyl vinyl ether

Conditions
ConditionsYield
With sodium at 150℃;
1-chloro-hexan-3-ol
52418-81-2

1-chloro-hexan-3-ol

A

-butyl vinyl ether
111-34-2

-butyl vinyl ether

B

diethylene glycol dibutyl ether
112-73-2

diethylene glycol dibutyl ether

Conditions
ConditionsYield
With sodium hydroxide
chloroethylene
75-01-4

chloroethylene

sodium butanolate
2372-45-4

sodium butanolate

-butyl vinyl ether
111-34-2

-butyl vinyl ether

Conditions
ConditionsYield
at 100℃;
chloroethylene
75-01-4

chloroethylene

potassium n-butoxide
3999-70-0

potassium n-butoxide

-butyl vinyl ether
111-34-2

-butyl vinyl ether

Conditions
ConditionsYield
at 100℃;
1-(2-bromoethoxy)butane
6550-99-8

1-(2-bromoethoxy)butane

-butyl vinyl ether
111-34-2

-butyl vinyl ether

Conditions
ConditionsYield
With sodium hydroxide
1-(2-bromoethoxy)butane
6550-99-8

1-(2-bromoethoxy)butane

A

-butyl vinyl ether
111-34-2

-butyl vinyl ether

B

diethylene glycol dibutyl ether
112-73-2

diethylene glycol dibutyl ether

Conditions
ConditionsYield
With sodium hydroxide
n-butyl 1-chloroethyl ether
3450-47-3

n-butyl 1-chloroethyl ether

N,N-dicyclohexyl-N-ethylamine
7175-49-7

N,N-dicyclohexyl-N-ethylamine

-butyl vinyl ether
111-34-2

-butyl vinyl ether

n-butyl 1-chloroethyl ether
3450-47-3

n-butyl 1-chloroethyl ether

N,N-dimethyl-aniline
121-69-7

N,N-dimethyl-aniline

A

-butyl vinyl ether
111-34-2

-butyl vinyl ether

B

butan-1-ol
71-36-3

butan-1-ol

1,2-dichloro-ethane
107-06-2

1,2-dichloro-ethane

sodium butanolate
2372-45-4

sodium butanolate

-butyl vinyl ether
111-34-2

-butyl vinyl ether

diethyl acetal
105-57-7

diethyl acetal

butan-1-ol
71-36-3

butan-1-ol

-butyl vinyl ether
111-34-2

-butyl vinyl ether

Conditions
ConditionsYield
at 320℃; beim Leiten ueber mit wss. Natronlauge vorbehandeltes Kieselgur;
4-(vinyloxy)butan-1-ol
17832-28-9

4-(vinyloxy)butan-1-ol

A

2-methyl-[1,3]dioxepane
4469-25-4

2-methyl-[1,3]dioxepane

B

-butyl vinyl ether
111-34-2

-butyl vinyl ether

C

Butane-1,4-diol
110-63-4

Butane-1,4-diol

Conditions
ConditionsYield
With potassium hydroxide at 180℃; Product distribution;
aluminium trichloride
7446-70-0

aluminium trichloride

1-(2-chloroethoxy)butane
10503-96-5

1-(2-chloroethoxy)butane

benzene
71-43-2

benzene

-butyl vinyl ether
111-34-2

-butyl vinyl ether

dibutyl acetal
871-22-7

dibutyl acetal

boric acid-asbestos

boric acid-asbestos

-butyl vinyl ether
111-34-2

-butyl vinyl ether

Conditions
ConditionsYield
at 380 - 410℃;
1,1-dibutoxy-2-chloro-ethane
17437-27-3

1,1-dibutoxy-2-chloro-ethane

sodium

sodium

-butyl vinyl ether
111-34-2

-butyl vinyl ether

Conditions
ConditionsYield
at 150℃;
1-(2-bromoethoxy)butane
6550-99-8

1-(2-bromoethoxy)butane

sodium hydroxide

sodium hydroxide

A

-butyl vinyl ether
111-34-2

-butyl vinyl ether

B

diethylene glycol dibutyl ether
112-73-2

diethylene glycol dibutyl ether

2-butoxyethyl N,N-dimethylcarbamate

2-butoxyethyl N,N-dimethylcarbamate

A

-butyl vinyl ether
111-34-2

-butyl vinyl ether

B

carbon dioxide
124-38-9

carbon dioxide

C

dimethyl amine
124-40-3

dimethyl amine

Conditions
ConditionsYield
at 389.6 - 420.5℃; Kinetics;
2-Butoxyethanol
111-76-2

2-Butoxyethanol

-butyl vinyl ether
111-34-2

-butyl vinyl ether

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: dimethylaniline; diethyl ether; PBr3
2: NaOH
View Scheme
Multi-step reaction with 2 steps
1: dimethylaniline; diethyl ether; PBr3
2: NaOH
View Scheme
vinyl propyl ether
764-47-6

vinyl propyl ether

butan-1-ol
71-36-3

butan-1-ol

-butyl vinyl ether
111-34-2

-butyl vinyl ether

Conditions
ConditionsYield
With [2,2]bipyridinyl; palladium diacetate In acetonitrile at 60℃; for 6h; Reagent/catalyst;
calcium carbide
75-20-7

calcium carbide

butan-1-ol
71-36-3

butan-1-ol

-butyl vinyl ether
111-34-2

-butyl vinyl ether

Conditions
ConditionsYield
With potassium fluoride; water; potassium hydroxide In neat (no solvent) at 150℃; for 13h; Autoclave;
4-tert-butyl benzyl vinyl ether
64022-41-9

4-tert-butyl benzyl vinyl ether

butan-1-ol
71-36-3

butan-1-ol

A

-butyl vinyl ether
111-34-2

-butyl vinyl ether

B

4-tert-Butylbenzyl alcohol
877-65-6

4-tert-Butylbenzyl alcohol

Conditions
ConditionsYield
With bathophenanthroline; copper diacetate at 120℃; for 24h; Schlenk technique; Inert atmosphere;
-butyl vinyl ether
111-34-2

-butyl vinyl ether

propargyl alcohol
107-19-7

propargyl alcohol

3-(1-butoxy-ethoxy)-propyne
871-12-5

3-(1-butoxy-ethoxy)-propyne

Conditions
ConditionsYield
With trifluoroacetic acid at 20 - 60℃; for 0.5h;100%
With hydrogenchloride78%
With hydrogenchloride50%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

1-bromo-3-aza-4-oxo-5-thiaheptanoic acid
137914-54-6

1-bromo-3-aza-4-oxo-5-thiaheptanoic acid

(2-Bromo-ethylcarbamoylsulfanyl)-acetic acid 1-butoxy-ethyl ester

(2-Bromo-ethylcarbamoylsulfanyl)-acetic acid 1-butoxy-ethyl ester

Conditions
ConditionsYield
In benzene at 50℃; for 1h;100%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

N-(p-nitrophenyl)-5-methyl-2-methylsulfonyl-3-thiophenecarbohydrazonoyl chloride
165066-12-6

N-(p-nitrophenyl)-5-methyl-2-methylsulfonyl-3-thiophenecarbohydrazonoyl chloride

5-Butoxy-3-(2-methanesulfonyl-5-methyl-thiophen-3-yl)-1-(4-nitro-phenyl)-4,5-dihydro-1H-pyrazole
165066-17-1

5-Butoxy-3-(2-methanesulfonyl-5-methyl-thiophen-3-yl)-1-(4-nitro-phenyl)-4,5-dihydro-1H-pyrazole

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 4.5h;100%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

Methyl 8-(phenylmethoxy)-4-<<(trifluoromethyl)sulfonyl>oxy>-2-naphthalenecarboxylate
144003-47-4

Methyl 8-(phenylmethoxy)-4-<<(trifluoromethyl)sulfonyl>oxy>-2-naphthalenecarboxylate

Methyl 4-(1-butoxyvinyl)-8-(phenylmethoxy)-2-naphthalenecarboxylate

Methyl 4-(1-butoxyvinyl)-8-(phenylmethoxy)-2-naphthalenecarboxylate

Conditions
ConditionsYield
With triethylamine; palladium diacetate; 1,3-bis-(diphenylphosphino)propane In N,N-dimethyl-formamide at 60℃; for 24h;100%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

methyl [(diphenylmethyl)imino] acetate N-oxide
77486-11-4, 77486-12-5, 160030-82-0

methyl [(diphenylmethyl)imino] acetate N-oxide

methyl [5-(n-butyloxy)-2-diphenylmethylisoxazolidin-3-yl]carboxylate

methyl [5-(n-butyloxy)-2-diphenylmethylisoxazolidin-3-yl]carboxylate

Conditions
ConditionsYield
With Eu(fod)3 In 1,2-dichloro-ethane at 20℃; for 6h;100%
With Eu(fod)3 In 1,2-dichloro-ethane for 6h; Ambient temperature; Yield given;
-butyl vinyl ether
111-34-2

-butyl vinyl ether

ethenyltrimethylsilane
754-05-2

ethenyltrimethylsilane

A

((Z)-2-Butoxy-vinyl)-trimethyl-silane

((Z)-2-Butoxy-vinyl)-trimethyl-silane

B

((E)-2-Butoxy-vinyl)-trimethyl-silane

((E)-2-Butoxy-vinyl)-trimethyl-silane

Conditions
ConditionsYield
Grubbs catalyst first generation In benzene at 60℃; for 24h; cross-metathesis; Title compound not separated from byproducts;A n/a
B 100%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

7-trifluoromethyl-3-methoxycarbonyl-4H-1,2-benzoxazine
538342-24-4

7-trifluoromethyl-3-methoxycarbonyl-4H-1,2-benzoxazine

C14H17F3O2

C14H17F3O2

Conditions
ConditionsYield
In toluene at 120℃; for 8h; Diels-Alder reaction;100%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

7-cyano-3-methoxycarbonyl-4H-1,2-benzoxazine
538342-25-5

7-cyano-3-methoxycarbonyl-4H-1,2-benzoxazine

C14H17NO2

C14H17NO2

Conditions
ConditionsYield
In toluene at 120℃; for 8h; Diels-Alder reaction;100%
1,1,1-trifluoromethanesulfonic acid 2-methoxyquinolin-8-yl ester
642477-88-1

1,1,1-trifluoromethanesulfonic acid 2-methoxyquinolin-8-yl ester

-butyl vinyl ether
111-34-2

-butyl vinyl ether

8-(1-butoxy-vinyl)-2-methoxy-quinoline
642478-21-5

8-(1-butoxy-vinyl)-2-methoxy-quinoline

Conditions
ConditionsYield
Stage #1: 1,1,1-trifluoromethanesulfonic acid 2-methoxyquinolin-8-yl ester; -butyl vinyl ether With N-ethyl-N,N-diisopropylamine; palladium diacetate; 1,3-bis-(diphenylphosphino)propane In DMF (N,N-dimethyl-formamide) at 60℃; for 18h;
Stage #2: With N-Bromosuccinimide In tetrahydrofuran; water for 1h;
100%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

2-[3-(2-hydroxy-2-phenylethyl)trisulfanyl]-1-phenyl-1-ethanol
1278475-40-3

2-[3-(2-hydroxy-2-phenylethyl)trisulfanyl]-1-phenyl-1-ethanol

2-{3-[2-(1-butoxyethoxy)-2-phenylethyl]trisulfanyl}-1-phenylethyl 1-butoxyethyl ether
1278475-55-0

2-{3-[2-(1-butoxyethoxy)-2-phenylethyl]trisulfanyl}-1-phenylethyl 1-butoxyethyl ether

Conditions
ConditionsYield
Stage #1: -butyl vinyl ether; 2-[3-(2-hydroxy-2-phenylethyl)trisulfanyl]-1-phenyl-1-ethanol With trifluoroacetic acid In 1,2-dimethoxyethane at 20℃; for 12h;
Stage #2: With potassium carbonate In 1,2-dimethoxyethane at 20℃; for 1h;
100%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

bis(2-bromo-2-butoxyethyl) selenide
1332580-99-0

bis(2-bromo-2-butoxyethyl) selenide

Conditions
ConditionsYield
With selenium dibromide In tetrachloromethane at -20 - 20℃; regioselective reaction;100%
With selenium dibromide In tetrachloromethane at -20 - 20℃; regioselective reaction;98%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

((1-butoxy-2-methylprop-1-en-1-yl)oxy)trimethylsilane
158362-24-4

((1-butoxy-2-methylprop-1-en-1-yl)oxy)trimethylsilane

butyl 2,2-dimethyl-3-butenoate

butyl 2,2-dimethyl-3-butenoate

Conditions
ConditionsYield
With indium tribromide In 1,2-dichloro-ethane at -20℃; for 2h; regioselective reaction;100%
With gallium(III) bromide In 1,2-dichloro-ethane at 80℃; for 2h; Catalytic behavior; Kinetics; Reagent/catalyst; Solvent; Temperature;93%
8-(benzyloxy)-5-[(1R)-2-bromo-1-hydroxyethyl]quinolin-2(1H)-one
530084-79-8

8-(benzyloxy)-5-[(1R)-2-bromo-1-hydroxyethyl]quinolin-2(1H)-one

-butyl vinyl ether
111-34-2

-butyl vinyl ether

C24H28BrNO4
1585234-56-5

C24H28BrNO4

Conditions
ConditionsYield
With toluene-4-sulfonic acid In tetrahydrofuran; toluene at 20 - 25℃; for 0.5h; Molecular sieve;100%
With toluene-4-sulfonic acid In tetrahydrofuran; toluene at 20 - 25℃; for 0.5h; Molecular sieve;100%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

3,3-(ethylene-dioxy)-17β-cyano-17α-hydroxy-19-norpregna-5(10),9(11)-diene

3,3-(ethylene-dioxy)-17β-cyano-17α-hydroxy-19-norpregna-5(10),9(11)-diene

17α-[(±)1-(1-n-butyloxyl)ethyl]oxyl-17β-cyano-3,3-(ethylene-dioxy)-19-norpregna-5(10),9(11)-diene

17α-[(±)1-(1-n-butyloxyl)ethyl]oxyl-17β-cyano-3,3-(ethylene-dioxy)-19-norpregna-5(10),9(11)-diene

Conditions
ConditionsYield
With toluene-4-sulfonic acid In tetrahydrofuran at 20℃; for 4h; Cooling; Large scale;100%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

6-chloro-2,2'-bipyridine-4,4'-dicarboxylic acid dimethyl ester
1344146-04-8

6-chloro-2,2'-bipyridine-4,4'-dicarboxylic acid dimethyl ester

palladium diacetate
3375-31-3

palladium diacetate

6-acetyl-2,2'-bipyridine-4,4'-dicarboxylic acid di-n-butyl ester

6-acetyl-2,2'-bipyridine-4,4'-dicarboxylic acid di-n-butyl ester

Conditions
ConditionsYield
Stage #1: -butyl vinyl ether; 6-chloro-2,2'-bipyridine-4,4'-dicarboxylic acid dimethyl ester; palladium diacetate With 1,3-bis-(diphenylphosphino)propane; sodium hydrogencarbonate In butan-1-ol Inert atmosphere; Reflux;
Stage #2: With hydrogenchloride In methanol; water at 20℃; for 0.166667h;
100%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

3-methyl-phenol
108-39-4

3-methyl-phenol

1-(n-butoxy)-1-(3-methylphenoxy)ethane
93308-46-4

1-(n-butoxy)-1-(3-methylphenoxy)ethane

Conditions
ConditionsYield
With trifluoroacetic acid at 60 - 65℃;99%
With phosphoric acid at 20℃;
-butyl vinyl ether
111-34-2

-butyl vinyl ether

2-bromo-1-phenyl-ethanone oxime
14181-72-7, 17082-13-2, 17082-14-3

2-bromo-1-phenyl-ethanone oxime

6-butoxy-3-phenyl-1,2-oxazine
132868-21-4

6-butoxy-3-phenyl-1,2-oxazine

Conditions
ConditionsYield
With sodium carbonate In dichloromethane for 15h; Ambient temperature;99%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

2-hexen-1-ol
2305-21-7

2-hexen-1-ol

1-butoxy-1-(hex-2-enyl)oxy-2-iodoethane
154613-93-1

1-butoxy-1-(hex-2-enyl)oxy-2-iodoethane

Conditions
ConditionsYield
With N-iodo-succinimide In dichloromethane at -78 - 0℃;99%
Stage #1: -butyl vinyl ether; 2-hexen-1-ol In dichloromethane at 20℃; for 0.0833333h;
Stage #2: With N-iodo-succinimide In dichloromethane at -78 - 0℃; Further stages.;
99%
With N-iodo-succinimide In dichloromethane Addition;
iodobenzene
591-50-4

iodobenzene

-butyl vinyl ether
111-34-2

-butyl vinyl ether

1-(2-butoxy-1-ethenyl)benzene

1-(2-butoxy-1-ethenyl)benzene

Conditions
ConditionsYield
With poly(N-isopropylacerylamide)-SCS-PdCl; TEA In n-heptane; N,N-dimethyl acetamide; water at 95℃; for 10h; Heck coupling;99%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

phosphonic acid diethyl ester
762-04-9

phosphonic acid diethyl ester

O,O-diethyl (2-butoxyethyl)phosphonate
4219-15-2

O,O-diethyl (2-butoxyethyl)phosphonate

Conditions
ConditionsYield
With triethyl borane; oxygen In cyclohexane at 20℃; for 54h;99%
methanol
67-56-1

methanol

-butyl vinyl ether
111-34-2

-butyl vinyl ether

1-(2-iodo-1-methoxyethoxy)butane

1-(2-iodo-1-methoxyethoxy)butane

Conditions
ConditionsYield
With dicloroiodoisocyanuric acid at 20℃; for 0.0166667h; Darkness; regioselective reaction;99%
With triiodoisocyanuric acid at 20℃; for 0.0333333h;83%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

tri-n-butyl-tin hydride
688-73-3

tri-n-butyl-tin hydride

<2-Butyloxy-ethyl>-triisobutyl-zinn
51283-48-8

<2-Butyloxy-ethyl>-triisobutyl-zinn

Conditions
ConditionsYield
In neat (no solvent) other Radiation; under Ar; (60)Co-irradiation; 1.5:1 molar ratio (olefine:Sn-compound) ;25°C; GLC;99%
other Radiation; gamma-radiation;;99%
other Radiation; gamma-radiation;;99%
In not given other Radiation; γ-radiation;;
-butyl vinyl ether
111-34-2

-butyl vinyl ether

methyl 2-bromo-5-methoxybenzoate
35450-36-3

methyl 2-bromo-5-methoxybenzoate

methyl 2-acetyl-5-methoxy-benzoate
1217472-06-4

methyl 2-acetyl-5-methoxy-benzoate

Conditions
ConditionsYield
With triethylamine; palladium diacetate; triphenylphosphine In acetonitrile at 99℃; for 16.5h; Inert atmosphere;99%
methyl 2-(2-diazo-1,3-dioxohexyl)benzoate

methyl 2-(2-diazo-1,3-dioxohexyl)benzoate

-butyl vinyl ether
111-34-2

-butyl vinyl ether

1-butanoyl-7-endo-buthoxy-5-methoxy-8-oxabenzo[c]bicyclo[3.2.1]octan-2-one

1-butanoyl-7-endo-buthoxy-5-methoxy-8-oxabenzo[c]bicyclo[3.2.1]octan-2-one

Conditions
ConditionsYield
With dirhodium tetraacetate; nickel(II) perchlorate hexahydrate; (R)-N,N'-bis(4-methyl-2-quinolylmethylene)-1,1'-binaphthyl-2,2'-diamine In dichloromethane at 55℃; for 1h; Inert atmosphere; Molecular sieve; optical yield given as %ee; enantioselective reaction;99%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

N-tert-butoxycarbonyl-D-Phenylalaninol
106454-69-7

N-tert-butoxycarbonyl-D-Phenylalaninol

(+)-(R)-tert-butyl [1-phenyl-3-(vinyloxy)propan-2-yl]carbamate
1319741-22-4

(+)-(R)-tert-butyl [1-phenyl-3-(vinyloxy)propan-2-yl]carbamate

Conditions
ConditionsYield
With 1,10-Phenanthroline; palladium (II) trifluoroacetate; triethylamine at 75℃; for 12h; Inert atmosphere;99%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

dimethyl 2-(1,3-dioxoisoindolin-2-yl)-cyclopropane-1,1-dicarboxylate
1352653-03-2

dimethyl 2-(1,3-dioxoisoindolin-2-yl)-cyclopropane-1,1-dicarboxylate

dimethyl 2-butoxy-4-(1,3-dioxoisoindolin-2-yl)cyclopentane-1,1-dicarboxylate

dimethyl 2-butoxy-4-(1,3-dioxoisoindolin-2-yl)cyclopentane-1,1-dicarboxylate

Conditions
ConditionsYield
With tin(IV) chloride In dichloromethane at -78℃; for 1h; Inert atmosphere; optical yield given as %de; diastereoselective reaction;99%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

ethyl (E)-4-((2-(3-methoxy-3-oxoprop-1-enyloxy)phenyl)ethynyl)benzoate
1396510-82-9

ethyl (E)-4-((2-(3-methoxy-3-oxoprop-1-enyloxy)phenyl)ethynyl)benzoate

methyl (2SR,3SR)-2-butoxy-4-(4-(ethoxycarbonyl)phenyl)-2,3-dihydrobenzo[b]oxepine-3-carboxylate

methyl (2SR,3SR)-2-butoxy-4-(4-(ethoxycarbonyl)phenyl)-2,3-dihydrobenzo[b]oxepine-3-carboxylate

Conditions
ConditionsYield
With [bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I) In 1,2-dichloro-ethane at 50℃; for 6h; Inert atmosphere; diastereoselective reaction;99%
2-phenylpyridine
1008-89-5

2-phenylpyridine

-butyl vinyl ether
111-34-2

-butyl vinyl ether

C17H21NO

C17H21NO

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate In toluene at 80℃; for 12h; Temperature; Reagent/catalyst; Schlenk technique; Inert atmosphere;99%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

phenol
108-95-2

phenol

1-(n-butoxy-1-phenoxy)ethane
20682-70-6

1-(n-butoxy-1-phenoxy)ethane

Conditions
ConditionsYield
With trifluoroacetic acid at 60 - 65℃;98%
With hydrogenchloride In 1,4-dioxane at 25℃; Rate constant; Mechanism; other alcohols;
With sulfuric acid at 20℃;
methyl coumalate
6018-41-3

methyl coumalate

-butyl vinyl ether
111-34-2

-butyl vinyl ether

methyl 8-butoxy-3-oxo-2-oxabicyclo[2.2.2]oct-5-ene-6-carboxylate

methyl 8-butoxy-3-oxo-2-oxabicyclo[2.2.2]oct-5-ene-6-carboxylate

Conditions
ConditionsYield
In acetonitrile at 75℃; for 24h; Diels-Alder Cycloaddition; Sealed tube;98%
In nitromethane at 70 - 80℃; Yield given;

n-Butylvinylether Chemical Properties

Structure of n-Butylvinylether (CAS NO.111-34-2):

IUPAC Name: 1-ethenoxybutane 
Empirical Formula: C6H12O
Molecular Weight: 100.1589 
EINECS: 203-860-7 
Index of Refraction: 1.4
Molar Refractivity: 31.31 cm3
Molar Volume: 129 cm3
Polarizability: 12.41×10-24cm3
Surface Tension: 22 dyne/cm
Density: 0.776 g/cm3
Enthalpy of Vaporization: 31.58 kJ/mol 
Melting Point: −92 °C(lit.)
Boiling Point: 93.6 °C at 760 mmHg
Vapour Pressure: 55.8 mmHg at 25°C 
Water Solubility: 3 g/L (20 ºC) 
Physical Appearance: clear liquid
Synonyms of n-Butylvinylether (CAS NO.111-34-2): Butane, 1-(ethenyloxy)- ; Butil vinil eter ; Butoxyethene ; Butoxyethylene ; Ethenyl n-butyl ether ; Ether butylvinylique ; Ether, butyl vinyl ; Vinyl butyl ether ; Vinyl n-butyl ether ; n-n-Butylvinylether 

n-Butylvinylether Toxicity Data With Reference

1.    

skn-rbt 500 mg open MLD

    UCDS**    Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 6/28 ,1973.
2.    

eye-rbt 500 mg open

    AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
3.    

orl-rat LD50:10 g/kg

    UCDS**    Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 6/28 ,1972.
4.    

ihl-uns LC50:60 g/m3

    GTPZAB    Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 32 (10)(1988),25.
5.    

ihl-mus LC50:62 g/m3/2H

    85GMAT    Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,119.
6.    

skn-rbt LD50:4240 mg/kg

    AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.

n-Butylvinylether Consensus Reports

Reported in EPA TSCA Inventory.

n-Butylvinylether Safety Profile

Hazard Codes: FlammableF
Risk Statements: 11-19 
R11:Highly flammable. 
R19:May form explosive peroxides.
Safety Statements: 9-14-16-33 
S9:Keep container in a well-ventilated place. 
S14:Keep away from ... (a list of incompatible materials will follow). 
S16:Keep away from sources of ignition. 
S33:Take precautionary measures against static discharges.
RIDADR: UN 2352 3/PG 2
WGK Germany: 2
RTECS: KN5950000
HazardClass: 3
PackingGroup: II
Mildly toxic by ingestion, skin contact, and inhalation. A skin and eye irritant. A very dangerous fire hazard when exposed to HEAT or flame. To fight fire, use foam, CO2, dry chemical, alcohol foam. Moderately explosive by spontaneous chemical reaction. Can react with oxidizing materials. When HEATed to decomposition it emits acrid smoke and irritating fumes. See also ETHERS.

n-Butylvinylether Standards and Recommendations

DOT Classification:  3; Label: Flammable Liquid

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