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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Methyl 2-bromohexanoate Manufacturer/High quality/Best price/In stock

Cas:5445-19-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Methyl-2-Bromocaproate supplier in China

Cas:5445-19-2

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:Colorless liquid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai

Methyl 2-bromohexanoate

Cas:5445-19-2

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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EAST CHEMSOURCES LIMITED

Methyl 2-bromohexanoate Melting point: <-10℃ Boiling point: Flash point: 80.6 ℃ Relative density: 1.289 Refractive index: 1.455

Methyl 2-bromohexanoate

Cas:5445-19-2

Min.Order:1 Kilogram

FOB Price: $2.0 / 3.0

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Methyl 2-bromohexanoate

Cas:5445-19-2

Min.Order:1

Negotiable

Type:Other

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Bromohexanoic acid methyl ester

Cas:5445-19-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Win-Win chemical Co.Ltd

Stock products, own laboratory Appearance:Transparent colorless liquid Storage:normal Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:shanghai

Methyl 2-bromohexanoate Cas no.5445-19-2 98%

Cas:5445-19-2

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

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Jinan Finer Chemical Co., Ltd

Product Description Name Methyl 2-bromohexanoate CAS 5445-19-2 Assay 99% Appearance

Methyl 2-bromohexanoate

Cas:5445-19-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

Tianfu Chemical, built in 2009, is a professional supplier for API materials in China. With 10 years development, we have bulit our own factory and lab to produce a certain of products. And we have established stable business relationship

TIANFU CHEM 5445-19-2 Methyl 2-bromohexanoate

Cas:5445-19-2

Min.Order:1 Kilogram

FOB Price: $200.0

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

Methyl 2-bromohexanoate CAS NO 5445-19-2

Cas:5445-19-2

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

New productCAS 5445-19-2 with high-quality service

Cas:5445-19-2

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after the dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available &diam

Methyl 2-bromohexanoate CAS5445-19-2

Cas:5445-19-2

Min.Order:1 Metric Ton

FOB Price: $7.0 / 10.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

CAS Number 5445-19-2 Product Name Methyl 2-bromohexanoate Synonyms Methyl 2-bromohexanoate; Hexanoic Acid, 2-bromo-, Methyl Este

Methyl 2-bromohexanoate

Cas:5445-19-2

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Hubei Langyou International Trading Co., Ltd

1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:White Crystalline Powder Storage:Store in sealed conta

high quality 5445-19-2 Methyl 2-bromohexanoate with best price

Cas:5445-19-2

Min.Order:10 Gram

Negotiable

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Hexanoic acid,2-bromo-, methyl ester 5445-19-2

Cas:5445-19-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

Hexanoic acid,2-bromo-, methyl ester/ LIDE PHARMA- Factory supply / Best price

Cas:5445-19-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Lonwin Chemical Group Limited

Methyl 2-bromohexanoate factory CAS:5445-19-2 Specification Melting point: <-10℃ Boiling point: Flash point: 80.6 ℃ Relative density: 1.289 Refractive index: 1.455 We

Factory Supply Methyl 2-bromohexanoate factory

Cas:5445-19-2

Min.Order:1 Kilogram

Negotiable

Type:Other

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Hexanoic acid,2-bromo-, methyl ester

Cas:5445-19-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Methyl-2-Bromocaproate

Cas:5445-19-2

Min.Order:0

Negotiable

Type:Manufacturers

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Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

Methyl 2-bromohexanoate CAS 5445-19-2

Cas:5445-19-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Methyl 2-bromohexano

Cas:5445-19-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Methyl 2-bromohexano

Cas:5445-19-2

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Hexanoic acid,2-bromo-, methyl ester

Cas:5445-19-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products Methyl 2-bromohexanoate

Cas:5445-19-2

Min.Order:100 Gram

Negotiable

Type:Other

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SHENGZHIKAI TECHNOLOGY INDUSTRY CO., LTD

Company Profile SHENGZHIKAI TECHNOLOGY INDUSTRY CO., LTD is a high-tech enterprise dedicated to the fields of fine chemical products.The scope of products covers pharmaceutical intermediates, plant extracts, chemical reagent, animal p

factory supply Methyl 2-bromohexanoate CAS 5445-19-2

Cas:5445-19-2

Min.Order:1 Kilogram

FOB Price: $12.0 / 18.0

Type:Trading Company

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colourless to slightly yellow liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Applica

Hexanoic acid,2-bromo-, methyl ester

Cas:5445-19-2

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hebei Kunsui Technology Co., Ltd.

1. A strong scientific research team . 2. Stable quality (with a complete scientific research center and testing center to ensure the quality stability of each batch of products). 3. Rich export experience (with practical experience in exporting to m

Organic Intermediate Methyl 2-bromohexanoate CAS 5445-19-2

Cas:5445-19-2

Min.Order:1 Liter

FOB Price: $4.5 / 5.0

Type:Trading Company

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Methyl 2-bromohexanoate

Cas:5445-19-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

Methyl2-bromohexanoate

Cas:5445-19-2

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

Methyl 2-bromohexanoate Chemical Properties Boiling point 94°C/15mmHg(lit.) density 1.289 g/mL at 20 °C (lit.) refractive index n20/D 1.455 Fp 69 °C BRN 1722052 CAS DataBase Reference 5445-19-2(CAS DataBase Referenc

Methyl 2-Bromohexanoate

Cas:5445-19-2

Min.Order:1 Gram

FOB Price: $66.0

Type:Lab/Research institutions

inquiry

Synthetic route

methanol
67-56-1

methanol

hexanal
66-25-1

hexanal

A

methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

B

methyl hexanoate
106-70-7

methyl hexanoate

Conditions
ConditionsYield
Stage #1: hexanal With ammonium cerium (IV) nitrate; lithium bromide In neat liquid
Stage #2: methanol In neat liquid at 35 - 40℃; for 3.5h;
A 80%
B 10 %Chromat.
methyl 2-acetyl-2-bromohexanoate
73621-73-5

methyl 2-acetyl-2-bromohexanoate

methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

Conditions
ConditionsYield
With lithium perchlorate; triethylamine In diethyl ether for 5h; Ambient temperature;72%
methyl α-butylacetoacetate
32798-42-8

methyl α-butylacetoacetate

methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

Conditions
ConditionsYield
With sodium acetate; sodium bromide In methanol at 15℃; Electrochemical reaction;70%
Multi-step reaction with 2 steps
1: MgBr2, H2O2
2: 72 percent / LiClO4, Et3N / diethyl ether / 5 h / Ambient temperature
View Scheme
2-bromohexanoyl chloride
42768-46-7

2-bromohexanoyl chloride

methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

Conditions
ConditionsYield
With triethylamine; mercury In methanol; benzene69.7%
methyl hexanoate
106-70-7

methyl hexanoate

methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

Conditions
ConditionsYield
Stage #1: methyl hexanoate With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -78 - 0℃; for 0.583333h;
Stage #2: With N-Bromosuccinimide In tetrahydrofuran at -78 - 20℃;
51%
2-bromohexanoic acid
616-05-7

2-bromohexanoic acid

methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

Conditions
ConditionsYield
With diethyl ether
methanol
67-56-1

methanol

2-bromohexanoyl chloride
42768-46-7

2-bromohexanoyl chloride

methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

methanol
67-56-1

methanol

Hexanoyl chloride
142-61-0

Hexanoyl chloride

methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

Conditions
ConditionsYield
(i) (bromination), (ii) /BRN= 1098229/; Multistep reaction;
methyl hexanoate
106-70-7

methyl hexanoate

A

methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

B

methyl 5-bromohexanoate
41796-82-1

methyl 5-bromohexanoate

C

Methyl 4-bromohexanoate
78019-66-6

Methyl 4-bromohexanoate

D

methyl 3-bromohexanoate

methyl 3-bromohexanoate

Conditions
ConditionsYield
With N-hydroxyphthalimide; bromine; nitric acid; copper diacetate In acetic acid at 80℃; for 5h; Title compound not separated from byproducts.;
methyl hexanoate
106-70-7

methyl hexanoate

A

methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

B

methyl 6-bromohexanoate
14273-90-6

methyl 6-bromohexanoate

C

methyl 5-bromohexanoate
41796-82-1

methyl 5-bromohexanoate

D

Methyl 4-bromohexanoate
78019-66-6

Methyl 4-bromohexanoate

E

methyl 3-bromohexanoate

methyl 3-bromohexanoate

Conditions
ConditionsYield
With N-bromo-N-(t-butyl)-3,5-bis(trifluoromethyl)benzamide In benzene at 20℃; for 4h; Reagent/catalyst; Sealed tube; Irradiation; Inert atmosphere; Overall yield = 56.1 %Chromat.;
methanol
67-56-1

methanol

2-bromohexanoic acid
616-05-7

2-bromohexanoic acid

methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

Conditions
ConditionsYield
With toluene-4-sulfonic acid at 65℃; for 12h;
methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

α-Azidohexansaeure-methylester
81629-62-1

α-Azidohexansaeure-methylester

Conditions
ConditionsYield
With sodium azide; Aliquat 336 In water at 60℃; for 14h;99%
methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

salicylaldehyde
90-02-8

salicylaldehyde

methyl 2-(2-formylphenoxy)hexanoate
138320-26-0

methyl 2-(2-formylphenoxy)hexanoate

Conditions
ConditionsYield
Stage #1: salicylaldehyde With potassium carbonate In N,N-dimethyl-formamide; toluene at 60 - 70℃; for 0.5h;
Stage #2: methyl 2-bromohexanoate In N,N-dimethyl-formamide; toluene at 80 - 100℃; for 2h;
99%
With potassium carbonate; potassium iodide In DMF (N,N-dimethyl-formamide) at 80℃; for 4h; Product distribution / selectivity;98.6%
With potassium carbonate In DMF (N,N-dimethyl-formamide) at 80℃; for 4h; Product distribution / selectivity;98.9%
methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

methyl salicylate
119-36-8

methyl salicylate

methyl 2-(1-methoxycarbonylpentoxy)benzoate

methyl 2-(1-methoxycarbonylpentoxy)benzoate

Conditions
ConditionsYield
With potassium carbonate In acetonitrile for 16h; Heating / reflux;99%
methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

[(p-methylphenyl)sulfonylmethyl]isonitrile
38622-91-2, 36635-61-7

[(p-methylphenyl)sulfonylmethyl]isonitrile

methyl 2-tosylhexanoate
71512-23-7

methyl 2-tosylhexanoate

Conditions
ConditionsYield
With water; copper(II) bis(trifluoromethanesulfonate); caesium carbonate In 1,4-dioxane at 70℃; for 9h; Schlenk technique; Inert atmosphere;98%
methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

n-decanoyl chloride
112-13-0

n-decanoyl chloride

methyl 2-butyl-3-oxododecanoate

methyl 2-butyl-3-oxododecanoate

Conditions
ConditionsYield
With 1-methyl-1H-imidazole; titanium tetrachloride; triphenylphosphine In dichloromethane at -50 - -45℃; Ti-crossed Claisen condensation;96%
methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

2,3-oxynaphthoic acid phenylamide
92-77-3

2,3-oxynaphthoic acid phenylamide

C24H25NO4
1242053-83-3

C24H25NO4

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 92 - 94℃; for 4h; Williamson synthesis;96%
methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

7-hydroxy-6-iodo-2,2-dimethyl-4H-benzo[d][1,3]dioxin-4-one
1404435-50-2

7-hydroxy-6-iodo-2,2-dimethyl-4H-benzo[d][1,3]dioxin-4-one

methyl 2-((6-iodo-2,2-dimethyl-4-oxo-4H-benzo[d][1,3]dioxin-7-yl)oxy)hexanoate

methyl 2-((6-iodo-2,2-dimethyl-4-oxo-4H-benzo[d][1,3]dioxin-7-yl)oxy)hexanoate

Conditions
ConditionsYield
With potassium carbonate In dimethyl sulfoxide at 20℃;96%
methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

thiophenol
108-98-5

thiophenol

methyl 2-(phenylthio)hexanoate
75280-16-9

methyl 2-(phenylthio)hexanoate

Conditions
ConditionsYield
With sodium hydroxide In ethanol95%
With sodium hydroxide In ethanol for 18h;95%
methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

2-(4-hydroxyphenoxy)-2-methyl propionic acid ethyl ester
42806-90-6

2-(4-hydroxyphenoxy)-2-methyl propionic acid ethyl ester

C19H28O6
860262-39-1

C19H28O6

Conditions
ConditionsYield
With potassium carbonate In acetonitrile Heating / reflux;95%
methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

hydrocinnamic acid chloride
645-45-4

hydrocinnamic acid chloride

methyl 2-(3-phenylpropanoyl)hexanoate

methyl 2-(3-phenylpropanoyl)hexanoate

Conditions
ConditionsYield
With 1-methyl-1H-imidazole; titanium tetrachloride; triphenylphosphine In dichloromethane at -50 - -45℃; Ti-crossed Claisen condensation;94%
methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

5-chlorosalicyclaldehyde
635-93-8

5-chlorosalicyclaldehyde

methyl 2-(4-chloro-2-formyl-phenoxy)hexanoate
1323367-31-2

methyl 2-(4-chloro-2-formyl-phenoxy)hexanoate

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 2h; Inert atmosphere;94%
undec-10-enoyl chloride
38460-95-6

undec-10-enoyl chloride

methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

methyl 2-butyl-3-oxo-12-tridecenoate

methyl 2-butyl-3-oxo-12-tridecenoate

Conditions
ConditionsYield
With 1-methyl-1H-imidazole; titanium tetrachloride; triphenylphosphine In dichloromethane at -50 - -45℃; Ti-crossed Claisen condensation;93%
methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

5-Chlorovaleroyl chloride
1575-61-7

5-Chlorovaleroyl chloride

2-butyl-7-chloro-3-oxo-heptanoic acid methyl ester

2-butyl-7-chloro-3-oxo-heptanoic acid methyl ester

Conditions
ConditionsYield
With 1-methyl-1H-imidazole; titanium tetrachloride; triphenylphosphine In dichloromethane at -50 - -45℃; Ti-crossed Claisen condensation;93%
methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

4-fluoro-3-methyl benzenethiol
845790-87-6

4-fluoro-3-methyl benzenethiol

2-(4-fluoro-3-methyl-phenylsulfanyl)-hexanoic acid methyl ester
1043450-31-2

2-(4-fluoro-3-methyl-phenylsulfanyl)-hexanoic acid methyl ester

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; for 46h;92%
methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

methyl 8-chloro-8-oxooctanoate
41624-92-4

methyl 8-chloro-8-oxooctanoate

2-butyl-3-oxo-decanedioic acid dimethyl ester

2-butyl-3-oxo-decanedioic acid dimethyl ester

Conditions
ConditionsYield
With 1-methyl-1H-imidazole; titanium tetrachloride; triphenylphosphine In dichloromethane at -50 - -45℃; Ti-crossed Claisen condensation;91%
methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

α-naphthol
90-15-3

α-naphthol

C17H20O3
1242053-84-4

C17H20O3

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 92 - 94℃; for 4h; Williamson synthesis;91%
methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

1-(phenylethynyl)-2-(vinyloxy)-benzene
1393481-89-4

1-(phenylethynyl)-2-(vinyloxy)-benzene

methyl 2-butyl-1-phenyl-2,3-dihydro-1H-benzo[b]cyclopenta[d]furan-2-carboxylate

methyl 2-butyl-1-phenyl-2,3-dihydro-1H-benzo[b]cyclopenta[d]furan-2-carboxylate

Conditions
ConditionsYield
With tert.-butylhydroperoxide; tetrakis(actonitrile)copper(I) hexafluorophosphate; silver carbonate In N,N-dimethyl acetamide at 120℃; for 24h; Schlenk technique; Inert atmosphere;88%
methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

5-Nitrosalicylaldehyde
97-51-8

5-Nitrosalicylaldehyde

methyl 2-(2-formyl-4-nitrophenoxy)hexanoate
335153-23-6

methyl 2-(2-formyl-4-nitrophenoxy)hexanoate

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 92 - 94℃; for 3.5h;87%
With potassium carbonate In N,N-dimethyl-formamide
1,1-Diphenylethylene
530-48-3

1,1-Diphenylethylene

methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

methyl 2-(2,2-diphenylvinyl)hexanoate
1380341-61-6

methyl 2-(2,2-diphenylvinyl)hexanoate

Conditions
ConditionsYield
With potassium phosphate; tetrakis(triphenylphosphine)nickel(0); 1,3-bis-(diphenylphosphino)propane In toluene at 100℃; for 16h; Heck type reaction; Inert atmosphere;87%
methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

9-isopropyl-6-phenyl-9H-purine
1310063-64-9

9-isopropyl-6-phenyl-9H-purine

methyl 2-[3-(9-isopropyl-9H-purin-6-yl)phenyl]hexanoate

methyl 2-[3-(9-isopropyl-9H-purin-6-yl)phenyl]hexanoate

Conditions
ConditionsYield
With [Ru(O2CAd)2(p-cymene)]; potassium carbonate; triphenylphosphine In 1,4-dioxane at 40℃; for 20h;87%
With potassium phosphate; {bis(triphenylphosphine)ruthenium diacetate} In 1,4-dioxane at 100℃; for 18h; Inert atmosphere; Schlenk technique; chemoselective reaction;60%
oxytriphine
22020-69-5

oxytriphine

methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

C22H25NO3

C22H25NO3

Conditions
ConditionsYield
With Ru(mesitylCO2)2(p-cymene); potassium carbonate; triphenylphosphine In 1,4-dioxane at 60℃; for 20h;86%
methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

4-(2-methoxybenzyl)-6-methylpyridazin-3(2H)-one
126775-18-6

4-(2-methoxybenzyl)-6-methylpyridazin-3(2H)-one

methyl 2-(5-(2-methoxybenzyl)-3-methyl-6-oxopyridazin-1(6H)-yl)hexanoate

methyl 2-(5-(2-methoxybenzyl)-3-methyl-6-oxopyridazin-1(6H)-yl)hexanoate

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran; mineral oil at 50℃; for 5h;86%
methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

5-nitro-o-vanilline
17028-61-4

5-nitro-o-vanilline

methyl 2-(2-formyl-6-methoxy-4-nitrophenoxy)hexanoate
959416-85-4

methyl 2-(2-formyl-6-methoxy-4-nitrophenoxy)hexanoate

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 92 - 94℃; for 4h;85%
With potassium carbonate In N,N-dimethyl-formamide at 93 - 95℃; for 4h;
2-phenylpyrimidine
7431-45-0

2-phenylpyrimidine

methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

C17H20N2O2

C17H20N2O2

Conditions
ConditionsYield
With [Ru(O2CAd)2(p-cymene)]; potassium carbonate; triphenylphosphine In 1,4-dioxane at 40℃; for 20h;85%
4-bromo-1-phenyl-1H-pyrazole
15115-52-3

4-bromo-1-phenyl-1H-pyrazole

methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

C16H19BrN2O2

C16H19BrN2O2

Conditions
ConditionsYield
With [Ru(O2CAd)2(p-cymene)]; potassium carbonate; triphenylphosphine In 1,4-dioxane at 60℃; for 20h;84%
methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

methyl 2-(2-(phenylethynyl)benzyl)acrylate
1431563-05-1

methyl 2-(2-(phenylethynyl)benzyl)acrylate

dimethyl (2R*,8aS*)-2-butyl-3-phenyl-1,2,8,8a-tetrahydrocyclopenta[a]indene-2,8a-dicarboxylate

dimethyl (2R*,8aS*)-2-butyl-3-phenyl-1,2,8,8a-tetrahydrocyclopenta[a]indene-2,8a-dicarboxylate

Conditions
ConditionsYield
With tris[2-phenylpyridinato-C2,N]iridium(III); sodium carbonate In acetonitrile at 20℃; for 20h; Inert atmosphere; Photolysis;83%
methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

methyl 2-(4-methoxyphenyl)hexanoate

methyl 2-(4-methoxyphenyl)hexanoate

Conditions
ConditionsYield
With potassium phosphate; tetrakis(triphenylphosphine)nickel(0) In toluene at 80℃; for 16h;82%
methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

2-p-tolyl-pyrimidine
77232-13-4

2-p-tolyl-pyrimidine

C18H22N2O2

C18H22N2O2

Conditions
ConditionsYield
With [Ru(O2CAd)2(p-cymene)]; potassium carbonate; triphenylphosphine In 1,4-dioxane at 40℃; for 20h;82%
4-Methoxystyrene
637-69-4

4-Methoxystyrene

methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

N,N-dimethyl-aniline
121-69-7

N,N-dimethyl-aniline

methyl 2-(2-(4-(dimethylamino)phenyl)-2-(4-methoxyphenyl)ethyl)hexanoate

methyl 2-(2-(4-(dimethylamino)phenyl)-2-(4-methoxyphenyl)ethyl)hexanoate

Conditions
ConditionsYield
With tris(bipyridine)ruthenium(II) dichloride hexahydrate; potassium carbonate; copper(l) chloride In acetonitrile at 20℃; for 2h; Inert atmosphere; Irradiation; Schlenk technique;82%
methyl 2-bromohexanoate
5445-19-2

methyl 2-bromohexanoate

triethyl phosphite
122-52-1

triethyl phosphite

methyl 2-diethylphosphonohexanoate
94014-69-4

methyl 2-diethylphosphonohexanoate

Conditions
ConditionsYield
at 150℃; for 16h;81%
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