Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities
Cas:5445-19-2
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inquiryWelcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our
Cas:5445-19-2
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inquiryhigh quality Appearance:Colorless liquid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea Port:shanghai
Methyl 2-bromohexanoate Melting point: <-10℃ Boiling point: Flash point: 80.6 ℃ Relative density: 1.289 Refractive index: 1.455
Cas:5445-19-2
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inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Cas:5445-19-2
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inquiryStock products, own laboratory Appearance:Transparent colorless liquid Storage:normal Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:shanghai
Cas:5445-19-2
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inquiryProduct Description Name Methyl 2-bromohexanoate CAS 5445-19-2 Assay 99% Appearance
Cas:5445-19-2
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inquiryTianfu Chemical, built in 2009, is a professional supplier for API materials in China. With 10 years development, we have bulit our own factory and lab to produce a certain of products. And we have established stable business relationship
Cas:5445-19-2
Min.Order:1 Kilogram
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inquiryOur advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva
Cas:5445-19-2
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inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:5445-19-2
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inquiry1. Product advantages ♦ High purity, all above 98.5%, no impurities after the dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available &diam
Cas:5445-19-2
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inquiryCAS Number 5445-19-2 Product Name Methyl 2-bromohexanoate Synonyms Methyl 2-bromohexanoate; Hexanoic Acid, 2-bromo-, Methyl Este
Cas:5445-19-2
Min.Order:5 Metric Ton
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inquiry1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appearance:White Crystalline Powder Storage:Store in sealed conta
Cas:5445-19-2
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inquiry1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
Cas:5445-19-2
Min.Order:1 Kilogram
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inquiryAdvantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&
Cas:5445-19-2
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inquiryMethyl 2-bromohexanoate factory CAS:5445-19-2 Specification Melting point: <-10℃ Boiling point: Flash point: 80.6 ℃ Relative density: 1.289 Refractive index: 1.455 We
Cas:5445-19-2
Min.Order:1 Kilogram
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Type:Other
inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
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inquiryBest quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia
1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie
Cas:5445-19-2
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inquiryHangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
Cas:5445-19-2
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inquiryOur Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We
J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
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inquiryChemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff
Cas:5445-19-2
Min.Order:100 Gram
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inquiryCompany Profile SHENGZHIKAI TECHNOLOGY INDUSTRY CO., LTD is a high-tech enterprise dedicated to the fields of fine chemical products.The scope of products covers pharmaceutical intermediates, plant extracts, chemical reagent, animal p
Cas:5445-19-2
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inquirySuperior quality, moderate price & quick delivery. Appearance:colourless to slightly yellow liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Applica
Cas:5445-19-2
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inquiry1. A strong scientific research team . 2. Stable quality (with a complete scientific research center and testing center to ensure the quality stability of each batch of products). 3. Rich export experience (with practical experience in exporting to m
Cas:5445-19-2
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inquiryProduct Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,
Cas:5445-19-2
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inquiryGMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,
Methyl 2-bromohexanoate Chemical Properties Boiling point 94°C/15mmHg(lit.) density 1.289 g/mL at 20 °C (lit.) refractive index n20/D 1.455 Fp 69 °C BRN 1722052 CAS DataBase Reference 5445-19-2(CAS DataBase Referenc
Cas:5445-19-2
Min.Order:1 Gram
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Type:Lab/Research institutions
inquiryConditions | Yield |
---|---|
Stage #1: hexanal With ammonium cerium (IV) nitrate; lithium bromide In neat liquid Stage #2: methanol In neat liquid at 35 - 40℃; for 3.5h; | A 80% B 10 %Chromat. |
methyl 2-acetyl-2-bromohexanoate
methyl 2-bromohexanoate
Conditions | Yield |
---|---|
With lithium perchlorate; triethylamine In diethyl ether for 5h; Ambient temperature; | 72% |
methyl α-butylacetoacetate
methyl 2-bromohexanoate
Conditions | Yield |
---|---|
With sodium acetate; sodium bromide In methanol at 15℃; Electrochemical reaction; | 70% |
Multi-step reaction with 2 steps 1: MgBr2, H2O2 2: 72 percent / LiClO4, Et3N / diethyl ether / 5 h / Ambient temperature View Scheme |
2-bromohexanoyl chloride
methyl 2-bromohexanoate
Conditions | Yield |
---|---|
With triethylamine; mercury In methanol; benzene | 69.7% |
Conditions | Yield |
---|---|
Stage #1: methyl hexanoate With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at -78 - 0℃; for 0.583333h; Stage #2: With N-Bromosuccinimide In tetrahydrofuran at -78 - 20℃; | 51% |
diazomethane
2-bromohexanoic acid
methyl 2-bromohexanoate
Conditions | Yield |
---|---|
With diethyl ether |
Conditions | Yield |
---|---|
(i) (bromination), (ii) /BRN= 1098229/; Multistep reaction; |
methyl hexanoate
A
methyl 2-bromohexanoate
B
methyl 5-bromohexanoate
C
Methyl 4-bromohexanoate
Conditions | Yield |
---|---|
With N-hydroxyphthalimide; bromine; nitric acid; copper diacetate In acetic acid at 80℃; for 5h; Title compound not separated from byproducts.; |
methyl hexanoate
A
methyl 2-bromohexanoate
B
methyl 6-bromohexanoate
C
methyl 5-bromohexanoate
D
Methyl 4-bromohexanoate
Conditions | Yield |
---|---|
With N-bromo-N-(t-butyl)-3,5-bis(trifluoromethyl)benzamide In benzene at 20℃; for 4h; Reagent/catalyst; Sealed tube; Irradiation; Inert atmosphere; Overall yield = 56.1 %Chromat.; |
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid at 65℃; for 12h; |
methyl 2-bromohexanoate
α-Azidohexansaeure-methylester
Conditions | Yield |
---|---|
With sodium azide; Aliquat 336 In water at 60℃; for 14h; | 99% |
methyl 2-bromohexanoate
salicylaldehyde
methyl 2-(2-formylphenoxy)hexanoate
Conditions | Yield |
---|---|
Stage #1: salicylaldehyde With potassium carbonate In N,N-dimethyl-formamide; toluene at 60 - 70℃; for 0.5h; Stage #2: methyl 2-bromohexanoate In N,N-dimethyl-formamide; toluene at 80 - 100℃; for 2h; | 99% |
With potassium carbonate; potassium iodide In DMF (N,N-dimethyl-formamide) at 80℃; for 4h; Product distribution / selectivity; | 98.6% |
With potassium carbonate In DMF (N,N-dimethyl-formamide) at 80℃; for 4h; Product distribution / selectivity; | 98.9% |
Conditions | Yield |
---|---|
With potassium carbonate In acetonitrile for 16h; Heating / reflux; | 99% |
methyl 2-bromohexanoate
[(p-methylphenyl)sulfonylmethyl]isonitrile
methyl 2-tosylhexanoate
Conditions | Yield |
---|---|
With water; copper(II) bis(trifluoromethanesulfonate); caesium carbonate In 1,4-dioxane at 70℃; for 9h; Schlenk technique; Inert atmosphere; | 98% |
Conditions | Yield |
---|---|
With 1-methyl-1H-imidazole; titanium tetrachloride; triphenylphosphine In dichloromethane at -50 - -45℃; Ti-crossed Claisen condensation; | 96% |
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 92 - 94℃; for 4h; Williamson synthesis; | 96% |
methyl 2-bromohexanoate
7-hydroxy-6-iodo-2,2-dimethyl-4H-benzo[d][1,3]dioxin-4-one
Conditions | Yield |
---|---|
With potassium carbonate In dimethyl sulfoxide at 20℃; | 96% |
Conditions | Yield |
---|---|
With sodium hydroxide In ethanol | 95% |
With sodium hydroxide In ethanol for 18h; | 95% |
methyl 2-bromohexanoate
2-(4-hydroxyphenoxy)-2-methyl propionic acid ethyl ester
C19H28O6
Conditions | Yield |
---|---|
With potassium carbonate In acetonitrile Heating / reflux; | 95% |
Conditions | Yield |
---|---|
With 1-methyl-1H-imidazole; titanium tetrachloride; triphenylphosphine In dichloromethane at -50 - -45℃; Ti-crossed Claisen condensation; | 94% |
methyl 2-bromohexanoate
5-chlorosalicyclaldehyde
methyl 2-(4-chloro-2-formyl-phenoxy)hexanoate
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 2h; Inert atmosphere; | 94% |
undec-10-enoyl chloride
methyl 2-bromohexanoate
Conditions | Yield |
---|---|
With 1-methyl-1H-imidazole; titanium tetrachloride; triphenylphosphine In dichloromethane at -50 - -45℃; Ti-crossed Claisen condensation; | 93% |
Conditions | Yield |
---|---|
With 1-methyl-1H-imidazole; titanium tetrachloride; triphenylphosphine In dichloromethane at -50 - -45℃; Ti-crossed Claisen condensation; | 93% |
methyl 2-bromohexanoate
4-fluoro-3-methyl benzenethiol
2-(4-fluoro-3-methyl-phenylsulfanyl)-hexanoic acid methyl ester
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 20℃; for 46h; | 92% |
methyl 2-bromohexanoate
methyl 8-chloro-8-oxooctanoate
Conditions | Yield |
---|---|
With 1-methyl-1H-imidazole; titanium tetrachloride; triphenylphosphine In dichloromethane at -50 - -45℃; Ti-crossed Claisen condensation; | 91% |
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 92 - 94℃; for 4h; Williamson synthesis; | 91% |
methyl 2-bromohexanoate
1-(phenylethynyl)-2-(vinyloxy)-benzene
Conditions | Yield |
---|---|
With tert.-butylhydroperoxide; tetrakis(actonitrile)copper(I) hexafluorophosphate; silver carbonate In N,N-dimethyl acetamide at 120℃; for 24h; Schlenk technique; Inert atmosphere; | 88% |
methyl 2-bromohexanoate
5-Nitrosalicylaldehyde
methyl 2-(2-formyl-4-nitrophenoxy)hexanoate
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 92 - 94℃; for 3.5h; | 87% |
With potassium carbonate In N,N-dimethyl-formamide |
1,1-Diphenylethylene
methyl 2-bromohexanoate
methyl 2-(2,2-diphenylvinyl)hexanoate
Conditions | Yield |
---|---|
With potassium phosphate; tetrakis(triphenylphosphine)nickel(0); 1,3-bis-(diphenylphosphino)propane In toluene at 100℃; for 16h; Heck type reaction; Inert atmosphere; | 87% |
methyl 2-bromohexanoate
9-isopropyl-6-phenyl-9H-purine
Conditions | Yield |
---|---|
With [Ru(O2CAd)2(p-cymene)]; potassium carbonate; triphenylphosphine In 1,4-dioxane at 40℃; for 20h; | 87% |
With potassium phosphate; {bis(triphenylphosphine)ruthenium diacetate} In 1,4-dioxane at 100℃; for 18h; Inert atmosphere; Schlenk technique; chemoselective reaction; | 60% |
Conditions | Yield |
---|---|
With Ru(mesitylCO2)2(p-cymene); potassium carbonate; triphenylphosphine In 1,4-dioxane at 60℃; for 20h; | 86% |
methyl 2-bromohexanoate
4-(2-methoxybenzyl)-6-methylpyridazin-3(2H)-one
Conditions | Yield |
---|---|
With sodium hydride In tetrahydrofuran; mineral oil at 50℃; for 5h; | 86% |
methyl 2-bromohexanoate
5-nitro-o-vanilline
methyl 2-(2-formyl-6-methoxy-4-nitrophenoxy)hexanoate
Conditions | Yield |
---|---|
With potassium carbonate In N,N-dimethyl-formamide at 92 - 94℃; for 4h; | 85% |
With potassium carbonate In N,N-dimethyl-formamide at 93 - 95℃; for 4h; |
Conditions | Yield |
---|---|
With [Ru(O2CAd)2(p-cymene)]; potassium carbonate; triphenylphosphine In 1,4-dioxane at 40℃; for 20h; | 85% |
Conditions | Yield |
---|---|
With [Ru(O2CAd)2(p-cymene)]; potassium carbonate; triphenylphosphine In 1,4-dioxane at 60℃; for 20h; | 84% |
methyl 2-bromohexanoate
methyl 2-(2-(phenylethynyl)benzyl)acrylate
Conditions | Yield |
---|---|
With tris[2-phenylpyridinato-C2,N]iridium(III); sodium carbonate In acetonitrile at 20℃; for 20h; Inert atmosphere; Photolysis; | 83% |
Conditions | Yield |
---|---|
With potassium phosphate; tetrakis(triphenylphosphine)nickel(0) In toluene at 80℃; for 16h; | 82% |
Conditions | Yield |
---|---|
With [Ru(O2CAd)2(p-cymene)]; potassium carbonate; triphenylphosphine In 1,4-dioxane at 40℃; for 20h; | 82% |
Conditions | Yield |
---|---|
With tris(bipyridine)ruthenium(II) dichloride hexahydrate; potassium carbonate; copper(l) chloride In acetonitrile at 20℃; for 2h; Inert atmosphere; Irradiation; Schlenk technique; | 82% |
methyl 2-bromohexanoate
triethyl phosphite
methyl 2-diethylphosphonohexanoate
Conditions | Yield |
---|---|
at 150℃; for 16h; | 81% |
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