4-Bromoethylbenzene supplier

Name
4-Bromoethylbenzene
EINECS 216-439-8
CAS No. 1585-07-5
Article Data120
CAS DataBase
Density 1.336 g/cm³
Solubility 23.3 mg/L at 25 °C in water
Melting Point -43 °C
Formula C₈H₉Br
Boiling Point 204.6 °C at 760 mmHg
Molecular Weight 185.063
Flash Point 71.2 °C
Transport Information UN 2810
Appearance Clear colourless to light yellow liquid
Safety 23-24/25
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms 1-Bromo-4-ethylbenzene;4-Ethyl-1-bromobenzene;4-Ethylphenylbromide;p-Ethylbromobenzene;Benzene,1-bromo-4-ethyl-;
PSA 0.00000
LogP 3.01150

Synthetic route

: 2039-82-9
1-bromo-4-ethenyl-benzene

: 1585-07-5
1-bromo-4-ethylbenzene

Conditions

Conditions	Yield
With C50H57IrN2P; hydrogen In dichloromethane at -78 - 20℃;	100%
With hydrogen In methanol; ethanol at 25℃; under 5171.62 Torr; for 18h; Inert atmosphere;	99%
With 0.42C23H20N4O42Cl(1-)Zn(2+)10.16H2O0.58Pd(2+)*0.58C23H20N4O4(1-); hydrogen In tetrahydrofuran at 20℃; under 760.051 Torr; for 1h;	99%

: 2039-82-9
1-bromo-4-ethenyl-benzene

: 241147-96-6
2-(4-(tert-butyl)phenyl)benzo[d][1,3,2]dioxaborole

A: 98-54-4
para-tert-butylphenol

B: 1585-07-5
1-bromo-4-ethylbenzene

Conditions

Conditions	Yield
With oxygen; hydrazine hydrate In acetonitrile at 32℃; under 760.051 Torr; for 3h; Schlenk technique;	A 99% B 89%

...Expand

: 766-96-1
4-bromo-1-ethynylbenzene

A: 2039-82-9
1-bromo-4-ethenyl-benzene

B: 1585-07-5
1-bromo-4-ethylbenzene

Conditions

Conditions	Yield
With hydrogen In hexane at 40℃; under 760.051 Torr; for 6h;	A 97% B 3%
With hydrogen; dimethyl sulfoxide In ethyl acetate at 20℃; under 760.051 Torr; for 24h;	A 88 %Spectr. B 9 %Spectr.

: 2039-82-9
1-bromo-4-ethenyl-benzene

A: 1585-07-5
1-bromo-4-ethylbenzene

B: 100-41-4
ethylbenzene

Conditions

Conditions	Yield
With iron(III) chloride; lithium aluminium tetrahydride; hydrogen In tetrahydrofuran at 18℃; under 750.075 Torr; for 6h; Inert atmosphere; Sealed tube;	A 94% B 12%
With palladium 10% on activated carbon; hydrogen In isopropyl alcohol at 50℃; under 4950.5 Torr;

: 99-90-1
para-bromoacetophenone

: 1585-07-5
1-bromo-4-ethylbenzene

Conditions

Conditions	Yield
With gallium(III) triflate; dimethylmonochlorosilane In dichloromethane at 20℃; for 1.5h;	89%
With lithium aluminium tetrahydride; diphosphorus tetraiodide In benzene for 3h; Heating;	87%
With titanium tetrachloride; dimethylamine borane In dichloromethane for 0.5h; Ambient temperature;	80%

: 41159-12-0
2-(4-bromophenyl)-2-methyl-1,3-dithiolane

: 1585-07-5
1-bromo-4-ethylbenzene

Conditions

Conditions	Yield
With sodium tetrahydroborate; nickel(II) chloride hexahydrate In tetrahydrofuran; methanol at 20℃; for 0.333333h;	86%

: 100-41-4
ethylbenzene

A: 1585-07-5
1-bromo-4-ethylbenzene

B: 1973-22-4
1-bromo-2-ethylbenzene

Conditions

Conditions	Yield
With oxygen; sodium bromide In dibutyl ether at 45℃; under 760.051 Torr; for 5h; Schlenk technique;	A 83% B 9%
With carbon dioxide; bromine at 40℃; under 187519 Torr; for 2h; Supercritical conditions; Green chemistry;	A 64% B 36%
With ammonium nitrate; N-Bromosuccinimide In acetonitrile for 8h;	A 53% B 30%

: 5391-88-8
1-(4-bromophenyl)ethanol

: 1585-07-5
1-bromo-4-ethylbenzene

Conditions

Conditions	Yield
With indium(III) chloride; diphenylsilyl chloride In dichloromethane at 20℃; for 3h;	83%
With formic acid; methanesulfonic acid; 1,2-bis((di-tert-butylphosphoryl)methyl)benzene; palladium(II) acetylacetonate; 1,2-bis[di(t-butyl)phosphinomethyl]benzene In 1,2-dichloro-ethane at 100℃; for 18h; Schlenk technique; Sealed tube; Inert atmosphere;	62 %Chromat.

: 100-41-4
ethylbenzene

: 1585-07-5
1-bromo-4-ethylbenzene

Conditions

Conditions	Yield
With sulfuric acid; sodium bromide at 60℃; for 2h;	81%
With sulfur dioxide; bromine; nitric acid; acetic acid Lichtausschluss;
(bromination);
With bromine; iodine; iron

: methyl (E)-2-(1-(4-bromophenyl)ethylidene)hydrazine-1-carboxylate

: 1585-07-5
1-bromo-4-ethylbenzene

Conditions

Conditions	Yield
With potassium hydroxide In 2,2'-[1,2-ethanediylbis(oxy)]bisethanol at 140℃; for 4h; Wolff-Kishner Reduction;	76%

: 1122-91-4
4-bromo-benzaldehyde

: 31729-70-1
bis(iodozinc)methane

: 1585-07-5
1-bromo-4-ethylbenzene

Conditions

Conditions	Yield
With Wilkinson's catalyst; hydrogen In tetrahydrofuran at 25℃; under 760.051 Torr;	76%

: C12H9BrN2O4S2

: 97-94-9
triethyl borane

: 1585-07-5
1-bromo-4-ethylbenzene

Conditions

Conditions	Yield
Pd(Cl2)dppf In tetrahydrofuran at 20℃; for 30h;	74%

: 97-94-9
triethyl borane

: 66107-30-0
4-bromophenyl trifluoromethanesulfonate

: 1585-07-5
1-bromo-4-ethylbenzene

Conditions

Conditions	Yield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; cesium acetate In tetrahydrofuran Suzuki-Miyaura cross-coupling; Reflux; Inert atmosphere;	72%

: 100-41-4
ethylbenzene

A: 1585-07-5
1-bromo-4-ethylbenzene

B: 585-71-7, 38661-81-3
(1-bromoethyl)benzne

Conditions

Conditions	Yield
With K10-montmorillonite clay; bromine In tetrachloromethane for 1.5h; Ambient temperature;	A 69% B 25%
With 1-butyl-3-methylimidazolium tribromide at 50℃; for 2.5h; regioselective reaction;

: 2039-82-9
1-bromo-4-ethenyl-benzene

: 201230-82-2
carbon monoxide

A: 1585-07-5
1-bromo-4-ethylbenzene

B: 40460-91-1
2-(4-bromophenyl)propanal

C: 80793-25-5
3-(4-bromophenyl)propanal

Conditions

Conditions	Yield
With hydrogen; N-dodecyl-N-(2-hydroxyethyl)-N,N-dimethylammonium bromide; {Rh(cod)[μ-S(CH2)3Si(OMe)3]}2; triphenylphosphine In water; butan-1-ol at 80℃; under 10350.8 Torr; for 6h; microemulsion/sol-gel;	A 1.3% B 51% C 16.5%

...Expand

: 100-41-4
ethylbenzene

A: 1585-07-5
1-bromo-4-ethylbenzene

B: 99-73-0
para-bromophenacyl bromide

Conditions

Conditions	Yield
With oxone; sodium bromide In water; acetonitrile at 50℃;	A 13% B 16%

: 74-96-4
ethyl bromide

: 108-86-1
bromobenzene

A: 1585-07-5
1-bromo-4-ethylbenzene

B: 1973-22-4
1-bromo-2-ethylbenzene

Conditions

Conditions	Yield
With aluminium at 80℃;

...Expand

: 64-67-5
diethyl sulfate

: 18620-02-5
(4-bromophenyl)magnesium bromide

: 1585-07-5
1-bromo-4-ethylbenzene

Conditions

Conditions	Yield
With diethyl ether; benzene

: 100-41-4
ethylbenzene

A: 1585-07-5
1-bromo-4-ethylbenzene

B: 66634-86-4
1-ethyl-2,4-dibromo-benzene

Conditions

Conditions	Yield
With sulfur dioxide; bromine; nitric acid; acetic acid Lichtausschluss;

: 106-37-6
1.4-dibromobenzene

: 75-03-6
ethyl iodide

: 1585-07-5
1-bromo-4-ethylbenzene

Conditions

Conditions	Yield
With sodium; benzene

: 589-16-2
4-aminoethylbenzene

: 1585-07-5
1-bromo-4-ethylbenzene

Conditions

Conditions	Yield
(i) NaNO2, H2SO4, (ii) CuSO4, Cu, NaBr, aq. H2SO4; Multistep reaction;

: 108-86-1
bromobenzene

: 74-85-1
ethene

A: 1585-07-5
1-bromo-4-ethylbenzene

B: 1973-22-4
1-bromo-2-ethylbenzene

C: 2725-82-8
1-bromo-3-ethylbenzene

Conditions

Conditions	Yield
H-ZSM-5 catalyst at 400℃; Product distribution; alkylation of benzene and momosubstituted benzenes with ethylene over H-ZSM-5 and mordenite-H catalysts; isomerization of ethylarenes over H-mordenite;

...Expand

: 2039-82-9
1-bromo-4-ethenyl-benzene

: 201230-82-2
carbon monoxide

A: 1585-07-5
1-bromo-4-ethylbenzene

B: 80793-25-5
3-(4-bromophenyl)propanal

C: (S)-2-(4-bromophenyl)propanal

D: (R)-2-(4-bromophenyl)propanal

Conditions

Conditions	Yield
With hydrogen; tin(ll) chloride; ((2S,4S)-N-(tert-butoxycarbonyl)-4-(diphenylphosphino)-2-{(diphenylphosphino)methyl}pyrrolidine)PtCl2 In benzene at 60℃; under 137044 Torr; for 8h; Yield given. Yields of byproduct given;

...Expand

: 100-41-4
ethylbenzene

A: 108-86-1
bromobenzene

B: 1585-07-5
1-bromo-4-ethylbenzene

C: 1973-22-4
1-bromo-2-ethylbenzene

Conditions

Conditions	Yield
With hydrogen bromide; dihydrogen peroxide at 50℃; Product distribution; Kinetics; Thermodynamic data; oth. temperature, var. stirring rate, var. ratio of reactants, E(activ.), ΔH(activ.), ΔS(activ.), ΔG(activ.);	A 1.6 % Chromat. B 73.3 % Chromat. C 22.2 % Chromat.
With hydrogenchloride; sodium hypochlorite; sodium bromide In water at 19.85℃; for 5h; Product distribution; Further Variations:; Temperatures;

...Expand

: 100-41-4
ethylbenzene

A: 1585-07-5
1-bromo-4-ethylbenzene

B: 1973-22-4
1-bromo-2-ethylbenzene

C: 2725-82-8
1-bromo-3-ethylbenzene

Conditions

Conditions	Yield
With bromine; iron(III) chloride In acetic acid at 25 - 75℃; Rate constant; Product distribution; other solvents (nitromethane, acetic anhydride), k (rel. to benzene);

...Expand

: 1973-22-4
1-bromo-2-ethylbenzene

A: 1585-07-5
1-bromo-4-ethylbenzene

B: 2725-82-8
1-bromo-3-ethylbenzene

Conditions

Conditions	Yield
H-mordenite at 250℃; Product distribution; alkylation of benzene and momosubstituted benzenes with ethylene over H-ZSM-5 and mordenite-H catalysts; isomerization of ethylarenes over H-mordenite;

: 292638-84-7
styrene

: 99-90-1
para-bromoacetophenone

A: 2039-82-9
1-bromo-4-ethenyl-benzene

B: 1585-07-5
1-bromo-4-ethylbenzene

: 1-Bromo-4-((1R,2R)-1-methyl-2-phenyl-cyclopropyl)-benzene

: C16H14Br2

Conditions

Conditions	Yield
In ethanol Mechanism; Zn(Hg), HCl;
With amalgamated zinc In ethanol at 20℃;

...Expand

: 99-90-1
para-bromoacetophenone

A: 2039-82-9
1-bromo-4-ethenyl-benzene

B: 1585-07-5
1-bromo-4-ethylbenzene

: 1-Bromo-4-((1R,2R)-1-methyl-2-phenyl-cyclopropyl)-benzene

: C16H14Br2

Conditions

Conditions	Yield
With styrene; amalgamated zinc In ethanol at 20℃;

...Expand

: 589-87-7
1,4-bromoiodobenzene

: 75-03-6
ethyl iodide

: 1585-07-5
1-bromo-4-ethylbenzene

Conditions

Conditions	Yield
With CuI*P(Et)3; naphthalen-1-yl-lithium 1.) THF, 25 deg C, 30 min, 2.) 25 deg C, 30 min; Yield given. Multistep reaction;

: 1585-07-5
1-bromo-4-ethylbenzene

: 159755-11-0
1-bromo-4-(1-bromoethyl)benzene

Conditions

Conditions	Yield
With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane at 90℃; for 3h;	100%
With bromine In tetrachloromethane at 50℃; for 1.25h; Irradiation;	98%
With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile) In tetrachloromethane at 90℃; for 3h;	68%

: 1585-07-5
1-bromo-4-ethylbenzene

: 98-80-6
phenylboronic acid

: 5707-44-8
4-ethylbiphenyl

Conditions

Conditions	Yield
With potassium tert-butylate In ethanol; water at 25℃; for 17h; Suzuki-Miyaura Coupling;	98%
With sodium carbonate; palladium on activated charcoal In ethanol at 80℃; for 19h;	96%
With potassium carbonate In water at 75℃; for 5h; Suzuki-Miyaura coupling; Inert atmosphere;	94%

: 75-77-4
chloro-trimethyl-silane

: 1585-07-5
1-bromo-4-ethylbenzene

: 17988-50-0
(4-ethylphenyl)trimethylsilane

Conditions

Conditions	Yield
Stage #1: 1-bromo-4-ethylbenzene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Stage #2: chloro-trimethyl-silane In tetrahydrofuran; hexane at -78 - 20℃;	98%

: 1585-07-5
1-bromo-4-ethylbenzene

: 115-19-5
2-methyl-but-3-yn-2-ol

: 155105-68-3
4-(4-ethylphenyl)-2-methylbut-3-yn-2-ol

Conditions

Conditions	Yield
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide at 60℃; for 24h; Sonogashira Cross-Coupling; Schlenk technique; Inert atmosphere;	98%

: 1585-07-5
1-bromo-4-ethylbenzene

: 99-90-1
para-bromoacetophenone

Conditions

Conditions	Yield
With tert.-butylhydroperoxide In water at 20℃; for 18h; Sealed tube;	97%
With Iron(III) nitrate nonahydrate; 1-hydroxy-pyrrolidine-2,5-dione; oxygen In benzonitrile at 90℃; for 30h;	97%
With Oxone; potassium bromide In nitromethane at 50℃; for 24h;	96%

: 1585-07-5
1-bromo-4-ethylbenzene

: 13049-40-6
4,4'-diethylbiphenyl

Conditions

Conditions	Yield
With caesium carbonate In water at 80℃; for 24h; Ullmann Condensation; Green chemistry;	97%
With 2Pd(2+)4Br(1-)C56H102N4; potassium carbonate at 75℃; for 12h; Ullmann Condensation;	92%
Multi-step reaction with 2 steps 1.1: n-butyllithium / tetrahydrofuran / 3 h / -78 °C 1.2: -78 - 20 °C 1.3: 1 h 2.1: caesium carbonate / 1-methyl-pyrrolidin-2-one; water / 20 h / 120 °C View Scheme
With potassium carbonate; benzyl alcohol In acetonitrile at 30℃; for 10h; Ullmann Condensation; Inert atmosphere; Irradiation;	99 %Chromat.

: 136918-14-4
phthalimide

: 1585-07-5
1-bromo-4-ethylbenzene

: 1436866-94-2
3-(4-ethylphenyl)-3-hydroxyisoindolin-1-one

Conditions

Conditions	Yield
Stage #1: 1-bromo-4-ethylbenzene With magnesium In tetrahydrofuran Stage #2: phthalimide In tetrahydrofuran; dichloromethane at 20℃; for 1.5h; Inert atmosphere;	96%

: 1585-07-5
1-bromo-4-ethylbenzene

: 1066-54-2
trimethylsilylacetylene

: (2-(4-ethylphenyl)ethynyl)trimethylsilane

Conditions

Conditions	Yield
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In acetonitrile at 120℃; for 0.0833333h; Sonogashira Cross-Coupling; Microwave irradiation; Sealed tube; Inert atmosphere;	95%
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; 1,8-diazabicyclo[5.4.0]undec-7-ene; 1,3,5,7-tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo[3.3.1.13,7]decane In N,N-dimethyl-formamide at 120℃; for 0.5h; microwave-assisted Sonogashira reaction; Microwave irradiation;	85%

: 1585-07-5
1-bromo-4-ethylbenzene

: 5720-07-0
4-methoxyphenylboronic acid

: 58244-47-6
4-ethyl-4'-methoxy-1,1'-biphenyl

Conditions

Conditions	Yield
With potassium phosphate tribasic heptahydrate; C31H25N2O4PPd In toluene at 80℃; for 2h;	93.5%

aqueous NH4 Cl: aqueous NH4 Cl

: 1585-07-5
1-bromo-4-ethylbenzene

: 17988-50-0
(4-ethylphenyl)trimethylsilane

Conditions

Conditions	Yield
With chloro-trimethyl-silane; magnesium In tetrahydrofuran	93%

: 1585-07-5
1-bromo-4-ethylbenzene

: 698-67-9
p-bromobenzamide

Conditions

Conditions	Yield
With tert.-butylhydroperoxide; ammonia; iodine In water at 100℃; for 3h; Sealed tube; Green chemistry;	93%
Stage #1: 1-bromo-4-ethylbenzene With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); water In ethyl acetate at 60℃; for 6h; Stage #2: With ammonium hydroxide; iodine In ethyl acetate; acetonitrile at 20℃; for 12h;	83%

: 1585-07-5
1-bromo-4-ethylbenzene

: 201230-82-2
carbon monoxide

: 123-54-6
acetylacetone

: 58278-92-5
1-(4-ethylphenyl)butane-1,3-dione

Conditions

Conditions	Yield
With dichloro(1,5-cyclooctadiene)palladium(II); triethylamine; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene; magnesium chloride In 1,4-dioxane at 80℃; for 18h; Sealed tube;	93%

...Expand

: 1585-07-5
1-bromo-4-ethylbenzene

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: 4748-78-1
4-ethylbenzylaldehyde

Conditions

Conditions	Yield
With samarium; copper(l) iodide at 20℃; for 4h; Inert atmosphere;	93%

: 112-45-8
10-Undecenal

: 1585-07-5
1-bromo-4-ethylbenzene

: 90900-80-4
1-Ethyl-4-undec-10-enyl-benzene

Conditions

Conditions	Yield
With ammonia; lithium In diethyl ether Ambient temperature;	92%

: 1585-07-5
1-bromo-4-ethylbenzene

: 70-55-3
toluene-4-sulfonamide

: 4-bromo-α-(p-toluenesulfonylamido)ethylbenzene

Conditions

Conditions	Yield
With [bis(acetoxy)iodo]benzene; iodine at 50℃; Inert atmosphere;	92%
With N-iodo-succinimide In dichloromethane at 20℃; for 16h; Irradiation;	74%
With tetrabutylammonium tetrafluoroborate In 1,2-dichloro-ethane at 20℃; for 2.5h; Electrochemical reaction; Inert atmosphere; regioselective reaction;	74%

: 1585-07-5
1-bromo-4-ethylbenzene

: 73644-95-8
1,2,4,5-tetrahydro-3-methyl-3H-3-benzazepin-2-one

: 1428449-40-4
1-(4-ethylphenyl)-4,5-dihydro-3-methyl-1H-benzo[d]azepin-2(3H)-one

Conditions

Conditions	Yield
With copper(l) iodide; palladium diacetate; sodium hydride; triphenylphosphine In 1,4-dioxane; N,N-dimethyl-formamide at 100℃; for 0.166667h; Microwave irradiation;	92%

: 1585-07-5
1-bromo-4-ethylbenzene

: 871949-46-1
2-trimethylsilyl ethane sulfonic acid azide

: C13H22BrNO2SSi

Conditions

Conditions	Yield
Stage #1: 1-bromo-4-ethylbenzene; 2-trimethylsilyl ethane sulfonic acid azide at -10℃; for 0.5h; Inert atmosphere; Molecular sieve; Stage #2: With C61H44F4N2O3Ru at -10℃; for 24h; Inert atmosphere; Molecular sieve;	92%

: 1585-07-5
1-bromo-4-ethylbenzene

: 62673-31-8
benzyl(bromo)zinc

: 620-85-9
1-benzyl-4-ethylbenzene

Conditions

Conditions	Yield
With SiliaCat DPP-Pd In tetrahydrofuran at 60℃; for 0.1h; Negishi Coupling; Inert atmosphere; Flow reactor;	92%

: 1585-07-5
1-bromo-4-ethylbenzene

: 5720-05-8
4-methylphenylboronic acid

: 76708-90-2
1-ethyl-4-(4-methylphenyl)benzene

Conditions

Conditions	Yield
With potassium carbonate In water; dimethyl sulfoxide at 60℃; for 24h; Suzuki-Miyaura coupling;	91%
With potassium carbonate In ethanol; water at 50℃; for 2h; Catalytic behavior; Suzuki-Miyaura Coupling;	89%
With water; triethylamine; Pd(OAc)2EnCatTM In N,N-dimethyl-formamide at 120℃; for 0.25h; Suzuki-Miyaura reaction; microwave irradiation;	72%

: 1585-07-5
1-bromo-4-ethylbenzene

: 5-bromo-4-(bromomethyl)-2-chloro-N-methoxy-N-methylbenzamide

: [5-bromo-4-(bromomethyl)-2-chlorophenyl](4-ethylphenyl)methanone

Conditions

Conditions	Yield
Stage #1: 1-bromo-4-ethylbenzene With magnesium In tetrahydrofuran; ethylene dibromide at 20 - 48℃; Large scale; Stage #2: 5-bromo-4-(bromomethyl)-2-chloro-N-methoxy-N-methylbenzamide In tetrahydrofuran; ethylene dibromide at 25℃; for 2h; Inert atmosphere; Large scale;	91%

: bis(tetrahydrofuran)tris(trimethylsilylmethyl)yttrium(III)

: 1585-07-5
1-bromo-4-ethylbenzene

: 4-(trimethylsilylmethyl)ethylbenzene

Conditions

Conditions	Yield
With tris-(dibenzylideneacetone)dipalladium(0); XPhos In toluene at 20℃; for 1h; Inert atmosphere; Schlenk technique;	91%

: 106-23-0, 26489-02-1
3,7-dimethyl-oct-6-enal

: 1585-07-5
1-bromo-4-ethylbenzene

: 93741-47-0
1-(3,7-Dimethyl-oct-6-enyl)-4-ethyl-benzene

Conditions

Conditions	Yield
With ammonia; lithium In diethyl ether	90%

: 141-27-5
3,7-dimethyl-2,6-octadienal

: 1585-07-5
1-bromo-4-ethylbenzene

: 93741-43-6
1-((E)-3,7-Dimethyl-octa-2,6-dienyl)-4-ethyl-benzene

Conditions

Conditions	Yield
With ammonia; lithium In diethyl ether for 1h;	90%

: 1585-07-5
1-bromo-4-ethylbenzene

: 61676-62-8
2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 1075719-87-7
2-(4-ethylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions

Conditions	Yield
With n-butyllithium; Triisopropyl borate In tetrahydrofuran; hexane at -60℃;	90%
With n-butyllithium In tetrahydrofuran; hexane at -60℃; Flow reactor;	87%

: 1585-07-5
1-bromo-4-ethylbenzene

: 292638-85-8
acrylic acid methyl ester

: (E)-methyl 3-(4-ethylphenyl)acrylate

Conditions

Conditions	Yield
With potassium carbonate In 1-methyl-pyrrolidin-2-one at 140℃; for 18h; Heck Reaction; Inert atmosphere;	90%

4-Bromoethylbenzene Chemical Properties

IUPAC Name: 1-Bromo-4-ethylbenzene
Canonical SMILES: CCC1=CC=C(C=C1)Br
InChI: InChI=1S/C8H9Br/c1-2-7-3-5-8(9)6-4-7/h3-6H,2H2,1H3
InChIKey: URFPRAHGGBYNPW-UHFFFAOYSA-N
Molecular Weight: 185.06106 [g/mol]
Molecular Formula: C₈H₉Br
XLogP3: 3.6
H-Bond Donor: 0
H-Bond Acceptor: 0
EINECS: 216-439-8
Product Categories: Aromatic Hydrocarbons (substituted) & Derivatives; Halides; Phenyls & Phenyl-Het; Benzene derivates; Bromine Compounds; 4-Alkylbromobenzenes (Building Blocks for Liquid Crystals); Building Blocks for Liquid Crystals; Functional Materials; Phenyls & Phenyl-Het; Aryl; C8; Halogenated Hydrocarbons
Stability: Stable. Incompatible with strong oxidizing agents.
Index of Refraction: 1.54
Molar Refractivity: 43.49 cm³
Molar Volume: 138.4 cm³
Surface Tension: 34 dyne/cm
Density: 1.336 g/cm³
Flash Point: 71.2 °C
Enthalpy of Vaporization: 42.29 kJ/mol
Boiling Point: 204.6 °C at 760 mmHg
Vapour Pressure: 0.373 mmHg at 25 °C
Water Solubility: 23.3 mg/L at 25 °C
Appearance: Clear colourless to light yellow liquid
Melting Point of p-Bromoethylbenzene (CAS NO.1585-07-5): -43 °C

4-Bromoethylbenzene Uses

p-Bromoethylbenzene (CAS NO.1585-07-5) is used as an organic reagent and a pharmaceutical intermediate.

4-Bromoethylbenzene Safety Profile

Safety Information of p-Bromoethylbenzene (CAS NO.1585-07-5):
Hazard Codes:Xi
Risk Statements:36/37/38
36/37/38:Irritating to eyes, respiratory system and skin
Safety Statements:23-24/25
23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer)
24/25:Avoid contact with skin and eyes
RIDADR:UN 2810
WGK Germany:3
Hazard Note:Irritant
TSCA:T
HS Code:29036990

4-Bromoethylbenzene Specification

p-Bromoethylbenzene (CAS NO.1585-07-5), its Synonyms are 1-Bromo-4-ethylbenzene ; 4-Ethylbromobenzene ; p-Ethylbromobenzene ; Benzene, 1-bromo-4-ethyl- .

Product Name

4-Bromoethylbenzene

Synthetic route

4-Bromoethylbenzene Chemical Properties

4-Bromoethylbenzene Uses

4-Bromoethylbenzene Safety Profile

4-Bromoethylbenzene Specification

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