Carbon tetrafluoride supplier

Name
Carbon tetrafluoride
EINECS 200-896-5
CAS No. 75-73-0
Article Data403
CAS DataBase
Density 1.315 g/cm³
Solubility
Melting Point -184 °C
Formula CF₄
Boiling Point -130 °C(lit.)
Molecular Weight 88.0046
Flash Point
Transport Information UN 1982 2.2
Appearance colourless gas
Safety 38
Risk Codes
Molecular Structure
Hazard Symbols F
Synonyms Carbontetrafluoride (8CI);Arcton 0;CFC 14;Carbon fluoride (CF4);Carbontetrafluoride (CF4);DF 14;FC 14;FC 14 (refrigerant);Freon 14;Freon R 14;Khladon 14;PFC 14;Perfluoromethane;R 14;R 14 (refrigerant);Refrigerant 14;Refrigerant R 14;Tetrafluoromethane;
PSA 0.00000
LogP 1.47570

Synthetic route

: 201230-82-2
carbon monoxide

A: 75-73-0
carbon tetrafluoride

B: 353-50-4
Carbonyl fluoride

Conditions

Conditions	Yield
With fluorine at 20 - 188℃; under 354.035 - 750.825 Torr; Product distribution / selectivity;	A n/a B 97.4%

: 75-72-9
chlorotrifluoromethane

: 75-73-0
carbon tetrafluoride

Conditions

Conditions	Yield
With hydrogen fluoride at 375℃;	95%
bei der Einw. einer Hochspannungs-Entladung;
With chromium fluoride; hydrogen fluoride
With iron(III) trifluoride; hydrogen fluoride

: 371-71-1
Perfluoro-2-azapropen

A: 75-73-0
carbon tetrafluoride

B: C5F10N3(1+)

Conditions

Conditions	Yield
With antimony pentafluoride at 60℃; for 6h;	A n/a B 95%

: 307-34-6
Perfluorooctane

: 75-73-0
carbon tetrafluoride

Conditions

Conditions	Yield
With hydrogen; fluorine at 0 - 200℃; Temperature;	95%
With fluorine at 200℃; under 760.051 Torr; Reagent/catalyst;	95%

: 3802-95-7
Perfluoromethyl azide

A: 75-73-0
carbon tetrafluoride

B: 76-16-4
Hexafluoroethane

C: 335-01-3
difluoramino trifluoromethane

Conditions

Conditions	Yield
With fluorine at 70℃; for 48h;	A 6% B 2% C 92%

...Expand

: 7440-44-0
pyrographite

: 7783-55-3
trifluorophosphane

A: 116-14-3
polytetrafluoroethylene

B: 75-73-0
carbon tetrafluoride

Conditions

Conditions	Yield
In neat (no solvent) react. of C with PF3 in a Ni-tube at 1100°C;;	A 90% B 9%

...Expand

: 13169-00-1
Methoxyallene

A: 75-73-0
carbon tetrafluoride

B: 59426-77-6
heptafluoropropyl trifluoromethyl ether

Conditions

Conditions	Yield
With fluorine; sodium fluoride at -100 - -10℃; for 12h;	A n/a B 89%

: 432-03-1
perfluorotrimethylamine

A: 75-73-0
carbon tetrafluoride

B: C5F10N3(1+)

Conditions

Conditions	Yield
With antimony pentafluoride at 60℃; for 720h;	A n/a B 85%

: 1001-56-5
buta-2,3-dienenitrile

A: 375-00-8
heptafluorobutyronitrile

B: 75-73-0
carbon tetrafluoride

Conditions

Conditions	Yield
With fluorine; sodium fluoride at -196 - -80℃; for 12h;	A 85% B n/a

: 463-49-0
1,2-propanediene

A: 75-73-0
carbon tetrafluoride

B: 76-19-7
freon-218

Conditions

Conditions	Yield
With fluorine; sodium fluoride at -100 - -10℃; for 12h;	A n/a B 84%

: 75-71-8
Dichlorodifluoromethane

: 75-73-0
carbon tetrafluoride

Conditions

Conditions	Yield
With hydrogen fluoride at 375℃;	83.5%
bei der Einw. einer Hochspannungs-Entladung;
With chromium fluoride; hydrogen fluoride
With iron(III) trifluoride; hydrogen fluoride

: 75-44-5
phosgene

: 7664-39-3
hydrogen fluoride

A: 373-91-1
hypofluorous acid trifluoromethyl ester

B: 75-73-0
carbon tetrafluoride

C: 353-50-4
Carbonyl fluoride

D: 75-72-9
chlorotrifluoromethane

E: 7782-50-5
chlorine

Conditions

Conditions	Yield
Electrochem. Process; water free HF, COCl2 dild. with He, 12-13°C, 7-8 V, current density: 1.7 A/dm2, electrolysis;	A 10% B 8% C 82% D <1 E <1

...Expand

: 358-23-6
trifluoromethylsulfonic anhydride

A: 75-73-0
carbon tetrafluoride

B: 335-05-7
Trifluoromethanesulfonyl fluoride

C: 3582-05-6
trifluoromethyl trifluoromethanesulfonate

Conditions

Conditions	Yield
With antimony pentafluoride at 25 - 60℃; for 0.25h; Yields of byproduct given;	A n/a B n/a C 80%
With antimony pentafluoride at 25 - 60℃; for 0.25h; Product distribution; Mechanism; var. Lewis acids, time, and temp.;	A n/a B n/a C 87 % Spectr.

...Expand

: 2314-97-8
iodotrifluoromethane

A: 75-73-0
carbon tetrafluoride

B: 105062-51-9
CF13IO2Te2

C Cl2, TeF6: Cl2, TeF6

Conditions

Conditions	Yield
With ClOTeF5 at -78℃; for 96h;	A n/a B 80% C n/a

...Expand

: 7783-54-2
nitrogen trifluoride

: 201230-82-2
carbon monoxide

A: 75-73-0
carbon tetrafluoride

B: 353-50-4
Carbonyl fluoride

C: 10102-43-9
nitrogen(II) oxide

D: 7789-25-5
nitrosyl fluoride

E: 10102-44-0
Nitrogen dioxide

Conditions

Conditions	Yield
nickel tube, equimolar amt., 825°C;	A n/a B 80% C n/a D n/a E n/a

...Expand

: 371-71-1
Perfluoro-2-azapropen

A: 75-73-0
carbon tetrafluoride

B: 334-99-6
trifluoronitrosomethane

C: 6141-72-6
perfluoro(2,4-dimethyl-3-oxa-2,4-diazapentane)

Conditions

Conditions	Yield
With difluoroether; fluorine; cesium fluoride at -78 - 25℃; for 48h; Addition; Decomposition;	A 11% B 12% C 77%

...Expand

: 10036-47-2
tetrafluorohydrazine

: 354-67-6
pentafluoro(1,1,2,2,2-pentafluoroethyl)-λ6-sulfane

A: 75-73-0
carbon tetrafluoride

B: 76-16-4
Hexafluoroethane

C: 354-80-3
Perfluoroethylamine

D: 7783-60-0
sulfur tetrafluoride

E: 2551-62-4
sulfur(VI) hexafluoride

Conditions

Conditions	Yield
NF3 formed too;	A n/a B n/a C 70% D n/a E n/a
NF3 formed too;	A n/a B n/a C 70% D n/a E n/a

...Expand

: 3518-65-8
monochloromethanesulfonyl chloride

A: 75-73-0
carbon tetrafluoride

B: 75-72-9
chlorotrifluoromethane

C: 335-05-7
Trifluoromethanesulfonyl fluoride

D: 64544-26-9
Chlorodifluoromethanesulfonyl fluoride

Conditions

Conditions	Yield
With hydrogen fluoride electrochemical fluorination;	A 4.5% B 69% C 5.7% D 52.9%

...Expand

: 75-44-5
phosgene

: 7664-39-3
hydrogen fluoride

: 7782-50-5
chlorine

A: 75-73-0
carbon tetrafluoride

B: 75-72-9
chlorotrifluoromethane

C: 75-71-8
Dichlorodifluoromethane

Conditions

Conditions	Yield
With catalyst : charcoal heating in autoclave, 425°C, 17 h, charcoal impregnated with FeCl3;	A 4% B 57% C 14%

...Expand

: 124-38-9
carbon dioxide

A: 373-91-1
hypofluorous acid trifluoromethyl ester

B: 75-73-0
carbon tetrafluoride

C: 353-50-4
Carbonyl fluoride

Conditions

Conditions	Yield
With fluorine at 224.84℃; under 1140.11 Torr; for 50h;	A 51.5% B 1.5% C 6%
With fluorine at 224.84℃; under 1140.11 Torr; for 72h;	A 32.1% B 4.6% C 11.1%

...Expand

: 426-03-9
difluoronitroacetic acid

A: 75-73-0
carbon tetrafluoride

B: 1185-11-1
dinitrodifluorometane

Conditions

Conditions	Yield
With xenon difluoride In dichloromethane at 5 - 10℃;	A n/a B 38%

: 813-40-1
chlorofluoronitroacetic acid

A: 75-73-0
carbon tetrafluoride

B: 40956-61-4
fluorodichloronitromethane

C: 19845-51-3
fluorochlorodinitromethane

Conditions

Conditions	Yield
With xenon difluoride In dichloromethane at 5 - 10℃;	A n/a B n/a C 28%
With xenon difluoride In dichloromethane at 5 - 10℃;

...Expand

: 66406-30-2
trifluoromethylselenium trifluoride

A: 75-73-0
carbon tetrafluoride

B: 75-72-9
chlorotrifluoromethane

C: 96401-50-2
(Trifluormethyl)selentetrafluoridchlorid

D Cl2, SeF6, SeF5Cl, SeF4: Cl2, SeF6, SeF5Cl, SeF4

Conditions

Conditions	Yield
With chlorine monofluoride at -100℃;	A n/a B n/a C 20% D n/a

...Expand

: 105062-51-9
CF13IO2Te2

A: 75-73-0
carbon tetrafluoride

B: 2314-97-8
iodotrifluoromethane

C

D (TeF4O)n, I(OTeF5)3: (TeF4O)n, I(OTeF5)3

Conditions

Conditions	Yield
at 25℃; for 2h;	A n/a B n/a C 17% D n/a

...Expand

: 75-46-7
trifluoromethan

A: 116-14-3
polytetrafluoroethylene

B: 75-73-0
carbon tetrafluoride

C: 76-19-7
freon-218

D: 116-15-4
perfluoropropylene

E: 76-16-4
Hexafluoroethane

Conditions

Conditions	Yield
With activated carbon supported potassium at 799.84℃; under 750.075 Torr; Pyrolysis; Inert atmosphere;	A 16.1% B n/a C n/a D 14.4% E n/a

...Expand

: 7782-41-4
fluorine

: 506-77-4
cyanogen chloride

A: 75-73-0
carbon tetrafluoride

B: 75-72-9
chlorotrifluoromethane

C: 75-71-8
Dichlorodifluoromethane

Conditions

Conditions	Yield
In neat (no solvent) byproducts: Cl2; at 94°C, 0.032 mol/h F2, further products; not isolated, detected by chromatography and IR-spectroscopy;	A <1 B 15% C 5%

...Expand

: 66406-30-2
trifluoromethylselenium trifluoride

A: 75-73-0
carbon tetrafluoride

B: 96401-49-9
(Trifluormethyl)selenpentafluorid

C SeF6, SeF4: SeF6, SeF4

Conditions

Conditions	Yield
With fluorine at -196℃; under 300 Torr; for 10h; Yields of byproduct given;	A n/a B 4% C n/a

...Expand

: 67-56-1
methanol

: 75-73-0
carbon tetrafluoride

Conditions

Conditions	Yield
With hydrogen fluoride Electrolysis.unter Verwendung von Nickelanoden und Eisenkathoden;

: 56-23-5
tetrachloromethane

: 75-73-0
carbon tetrafluoride

Conditions

Conditions	Yield
With arsenic; fluorine at 70℃;
With iodine; fluorine
With cobalt (III) fluoride; fluorine

: 373-91-1
hypofluorous acid trifluoromethyl ester

: 34557-54-5
methane

A: 75-73-0
carbon tetrafluoride

B: 75-10-5
Difluoromethane

C: 75-46-7
trifluoromethan

Conditions

Conditions	Yield
im UV-Licht;

...Expand

: 75-73-0
carbon tetrafluoride

: (trimethoxysilyl)dichlorosulfonylamine

: trimethoxysilyl bis(trifluoromethylsulfonyl)amine

Conditions

Conditions	Yield
Stage #1: (trimethoxysilyl)dichlorosulfonylamine With lithium hydride In diethyl ether at 0℃; for 2h; Stage #2: carbon tetrafluoride In diethyl ether	91%

: 4-[(6-acetoxyhexyl)sulfonyl]toluene

: 75-73-0
carbon tetrafluoride

: 4-[(6-acetoxyhexyl)sulfonyl]benzyl bromide

Conditions

Conditions	Yield
With N-Bromosuccinimide; dibenzoyl peroxide In nitrogen	71%

: 3982-91-0
trichlorothiophosphine

: 75-73-0
carbon tetrafluoride

A: 52826-97-8
PSCl2(1+)

B: CF2Cl3(1+)

C: PSCl3(1+)

D: 64710-27-6
Cl3FP(1+)

E: PCl3(1+)

Conditions

Conditions	Yield
In gas Kinetics; byproducts: CF2, CF2S, CClF2; High Pressure; ions were generated in an electron impact high-pressure ion source contg. CF4; the reagent ions were selected using a quadrupole mass filter before being injected into a region contg. He; at 298 K; CF2, CF2S, CClF2, CFS, PS were obtained; monitoring by quadrupole mass spectrometer at the end of the flow tube;	A 4% B 2% C 69% D n/a E 25%

...Expand

: 3982-91-0
trichlorothiophosphine

: 75-73-0
carbon tetrafluoride

A: PFCl2(1+)

B: 38264-02-7
SCF(1+)

C: 75601-84-2
PCl2(1+)

D: 81128-92-9
PS(1+)

E: 40640-70-8
fluorodichloromethyl(1+)

Conditions

Conditions	Yield
In gas Kinetics; byproducts: CFSCl3(1+), PFCl3(1+), CClS(1+); High Pressure; ions generated in an electron impact high-pressure source contg. CF4 were selected using a mass filter before being injected into a region contg. He; 298 K; CFSCl3(1+), PFCl3(1+), CClS(1+), CCl3F, PCl3, CClS, CClFS, PSCl, P, CS, PFCl2 were also obtained; monitoring by quadrupole mass spectrometer at the end of the flow tube;	A 15% B 64% C n/a D n/a E 9%

Yield

In gas Kinetics; byproducts: CFSCl3(1+), PFCl3(1+), CClS(1+); High Pressure; ions generated in an electron impact high-pressure source contg. CF4 were selected using a mass filter before being injected into a region contg. He; 298 K; CFSCl3(1+), PFCl3(1+), CClS(1+), CCl3F, PCl3, CClS, CClFS, PSCl, P, CS, PFCl2 were also obtained; monitoring by quadrupole mass spectrometer at the end of the flow tube;

A 15%
B 64%
C n/a
D n/a
E 9%

...Expand

: 3982-91-0
trichlorothiophosphine

: 75-73-0
carbon tetrafluoride

A: 52826-97-8
PSCl2(1+)

B: CF3(1+)*PSCl3=CF3*PSCl3(1+)

C: 64710-27-6
Cl3FP(1+)

D: 420-32-6
thiocarbonyl fluoride

E: 75-72-9
chlorotrifluoromethane

Conditions

Conditions	Yield
In gas Kinetics; High Pressure; the reagent ions were generated in an electron impact high-pressure ion source contg. CF4; the reagent ions were selected using a quadrupole mass filter before being injected into a drift region contg. helium carriergas; at 298 K; monitoring by quadrupole mass spectrometer at the end of the flow tube;	A 48% B 44% C 8% D n/a E n/a

...Expand

: 3982-91-0
trichlorothiophosphine

: 75-73-0
carbon tetrafluoride

A: 52826-97-8
PSCl2(1+)

B: PSCl(1+)

C: 81991-06-2
PCl(1+)

D: 75601-84-2
PCl2(1+)

E: 81128-92-9
PS(1+)

Conditions

Conditions	Yield
In gas Kinetics; byproducts: PSCl3(1+), F, SCl2; High Pressure; ions generated in an electron impact high-pressure ion source contg. CF4were selected using a quadrupole mass filter before being injected into a drift region contg. He; 298 K; PSCl3(1+), Cl2, ClF, SCl, F, Cl, SCl2 were also obtained; monitoring by quadrupole mass spectrometer at the end of the flow tube;	A 15% B 17% C 5% D 22% E 38%

...Expand

Carbon tetrafluoride Consensus Reports

Reported in EPA TSCA Inventory.

Carbon tetrafluoride Standards and Recommendations

DOT Classification: 2.2; Label: Nonflammable Gas

Carbon tetrafluoride Specification

The Carbon tetrafluoride, with the cas registry number 75-73-0, has the IUPAC name of tetrafluoromethane. This is a kind of colorless odourless gas and is slighly soluble in water. Then it is stable chemically but incompatible with zinc, alkaline earth metals, Group I metals, aluminium and its alloys. Besides, its product categories are various, including refrigerants; Organics; Chemical Synthesis; Compressed and Liquefied GasesMicro/Nanoelectronics; Electronic Chemicals; Gases; Synthetic Reagents.

The characteristics of this chemical are as follows: (1)ACD/LogP: 1.24; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.24; (4)ACD/LogD (pH 7.4): 1.24; (5)ACD/BCF (pH 5.5): 5.13; (6)ACD/BCF (pH 7.4): 5.13; (7)ACD/KOC (pH 5.5): 112.15; (8)ACD/KOC (pH 7.4): 112.15 ; (9)Index of Refraction: 1.169; (10)Molar Refractivity: 7.3 cm³; (11)Molar Volume: 66.8 cm³; (12)Polarizability: 2.89 ×10^-24 cm³; (13)Surface Tension: 6 dyne/cm; (14)Density: 1.315 g/cm³; (15)Enthalpy of Vaporization: 13.9 kJ/mol; (16)Vapour Pressure: 82600 mmHg at 25°C; (17)Exact Mass: 87.993613; (18)MonoIsotopic Mass: 87.993613; (19)Topological Polar Surface Area: 0; (20)Heavy Atom Count: 5; (21)Formal Charge: 0; (22)Complexity: 19.1.

Production method Carbon tetrafluoride is as below: difluoro-nitro-acetic acid could react to produce Carbon tetrafluoride, with the following condition: reagent: XeF₂; solvent: CH₂C_l2; reaction time: 5 - 10 ℃; yield: 38%.

As to its usage, it is widely applied in many ways. It could be used in making refrigerant, solvent, lubricating agent, electrical insulating material, coolant of; It could also used in producing low temperature liquid pressure gage or as the inert gases, or in lasing gas in all kinds of integrated semiconductor.

When deal with this chemical, you should be very cautious. Being a kind of highly flammable chemical, it may catch fire in contact with air, only needing brief contact with an ignition source, and has a very low flash point or evolve highly flammable gases in contact with water. And Carbon tetrafluoride may be narcotic at high concentrations and it may rupture violently and rocket under prolonged exposure to fire or heat the containers. Therefore, you should take the following instructions. In case of insufficient ventilation wear suitable respiratory equipment

In addition, you could obtain the molecular structure by converting the following datas:
(1)Canonical SMILES: C(F)(F)(F)F
(2)InChI: InChI=1S/CF4/c2-1(3,4)5
(3)InChIKey: TXEYQDLBPFQVAA-UHFFFAOYSA-N

Below are the toxicity information of this chemical:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
rat	LCLo	inhalation	895000ppm/15M (895000ppm)		U.S. Army, Chemical Corps Medical Laboratories Research Reports. Vol. #23, Pg. 1950,

Product Name

Carbon tetrafluoride

Synthetic route

Carbon tetrafluoride Consensus Reports

Carbon tetrafluoride Standards and Recommendations

Carbon tetrafluoride Specification

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