Titanous chloride supplier | CasNO.7705-07-9

Name
Titanous chloride
EINECS 231-728-9
CAS No. 7705-07-9
Article Data95
CAS DataBase
Density 1.2
Solubility Soluble
Melting Point -24 ºC
Formula Cl3Ti
Boiling Point 100 ºC
Molecular Weight 154.239
Flash Point
Transport Information
Appearance purple crystalline solid
Safety A corrosive irritant to skin, eyes, and mucous membranes. A severe corrosive because it liberates heat and hydrochloric acid upon contact with moisture. If spilled on skin, wipe off with dry cloth before applying water. May ignite spontaneously in air. Flammable when exposed to heat or flame. Reacts violently with K, HF. Experimental reproductive effects. When heated to decomposition it emits toxic fumes of Cl⁻. See also TITANIUM COMPOUNDS.
Risk Codes R35
Molecular Structure
Hazard Symbols
Synonyms Lynx 900;TAC 121; TAC 132; TAC 140; TAC 144; TAS 101; TEN 12; TGY 24; TOS 17; Titaniumchloride; Titanium trichloride; Titanium(III) chloride; Titanous chloride;Trichlorotitanium
PSA 0.00000
LogP 2.06850

Synthetic route

: 55527-82-7
bis(η6-toluene)titanium(0)

: 7550-45-0
titanium tetrachloride

: 7705-07-9
titanium(III) chloride

Conditions

Conditions	Yield
In n-heptane byproducts: CH3C6H5; under purified Ar atm.; soln. of TiCl4 in heptane added to soln. of Ti(η6-MeC6H5)2 in heptane; mixt. stirred for 18 h at room temp.; solid filtered; washed (heptane); dried (vac.); elem. anal.;	62%

: 7440-32-6
titanium

: 7647-14-5
sodium chloride

: 7705-07-9
titanium(III) chloride

: 7550-45-0
titanium tetrachloride

: 7439-95-4
magnesium

A: 7440-32-6
titanium

B: titanium chloride

C: 7705-07-9
titanium(III) chloride

D: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In neat (no solvent) Mg film exposing to TiCl4 at 1E-7 and 1E-6 Torr; monitoring by XPS;

...Expand

: 7550-45-0
titanium tetrachloride

: 7439-95-4
magnesium

: 7705-07-9
titanium(III) chloride

Conditions

Conditions	Yield
reaction is vigorous below red heat;;
reaction is vigorous below red heat;;

: 7440-32-6
titanium

: 7550-45-0
titanium tetrachloride

: 7429-90-5
aluminium

A: 7446-70-0
aluminium trichloride

B: aluminium chloride dimer

C: aluminum(I) chloride

D: TiAlCl5

E: 7705-07-9
titanium(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) at 1100 K; further product TiAlCl5; identification by mass spectrometry;

...Expand

: 7440-32-6
titanium

: 7550-45-0
titanium tetrachloride

: 7429-90-5
aluminium

A: 7446-70-0
aluminium trichloride

B: aluminium chloride dimer

C: 7705-07-9
titanium(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) at 900 K; identification by mass spectrometry;

...Expand

: 7440-32-6
titanium

: 7550-45-0
titanium tetrachloride

: 7429-90-5
aluminium

A: 7446-70-0
aluminium trichloride

B: aluminium chloride dimer

C: titanium chloride

D: 7705-07-9
titanium(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) at 1000 K; identification by mass spectrometry;

...Expand

: 7550-45-0
titanium tetrachloride

: 12775-96-1, 15158-11-9, 15721-63-8, 16941-75-6, 17493-86-6, 19498-52-3, 20499-83-6, 20499-84-7, 20499-85-8, 20499-86-9, 20573-10-8, 20573-11-9, 21595-51-7, 21595-52-8, 22206-52-6, 26445-28-3, 28959-95-7, 37362-93-9, 39417-05-5, 54603-16-6, 54603-23-5, 54603-32-6, 54603-40-6, 54603-48-4, 54603-81-5, 54603-89-3, 56316-56-4, 95985-91-4, 122297-32-9, 7440-50-8
copper

A: 7705-07-9
titanium(III) chloride

B: copper(l) chloride

Conditions

Conditions	Yield
In water room temp., exclusion of air;;

...Expand

: hydrogen

: 7550-45-0
titanium tetrachloride

A: 7647-01-0
hydrogenchloride

B: 7705-07-9
titanium(III) chloride

Conditions

Conditions	Yield
In gas Kinetics;

...Expand

: 7440-32-6
titanium

: 7550-45-0
titanium tetrachloride

: 7705-07-9
titanium(III) chloride

Conditions

Conditions	Yield
react. in closed tube at 890/440 K;
In neat (no solvent) 1100 K;
250 °C in tube;

: 7647-01-0
hydrogenchloride

: 7440-32-6
titanium

: 7705-07-9
titanium(III) chloride

Conditions

Conditions	Yield
In water
In hydrogenchloride metal dissoln. in concd. acid for 7 d;
In hydrogenchloride dissoln. of metallic titanium in distilled HCl under inert atmosphere; stored air-proof;

: 7550-45-0
titanium tetrachloride

: 7705-07-9
titanium(III) chloride

Conditions

Conditions	Yield
With tin In hydrogenchloride strong aq. HCl-soln.;
With C6H5CHOHCO2H byproducts: C6H5CHO, HCl, CO2; Irradiation (UV/VIS);
With sodium dithionite In not given byproducts: NaCl, SO2; in dild. acids;

: 97-93-8
triethylaluminum

: 7550-45-0
titanium tetrachloride

A: 7440-32-6
titanium

B: 32871-14-0
EtTiCl2

C: 7705-07-9
titanium(III) chloride

D: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In neat (no solvent) sample exposition to Al-compd. layer at 300 K for 10 min; monitoring by XPS;

...Expand

: 1333-74-0
hydrogen

: 7550-45-0
titanium tetrachloride

: 7705-07-9
titanium(III) chloride

Conditions

Conditions	Yield
With chlorine burning a flame of Cl2 and TiCl4-vapor in hydrogen atmosphere;

: 1333-74-0
hydrogen

: 7550-45-0
titanium tetrachloride

A: titanium chloride

B: 7782-50-5
chlorine

C: 7705-07-9
titanium(III) chloride

Conditions

Conditions	Yield
In gas Kinetics; byproducts: HCl; Irradiation (UV/VIS); stationary photolysis in a sealed quartz cell at 210°C; vac.distn.;

...Expand

: titanium(IV) oxide

: 7705-07-9
titanium(III) chloride

Conditions

Conditions	Yield
With C; alkali chlorides; Cl2 In neat (no solvent) byproducts: CO2; Electrochem. Process; at 700 - 930°C;;

: 7550-45-0
titanium tetrachloride

: 19287-45-7
diborane

A: titanium diboride

B: 7705-07-9
titanium(III) chloride

Conditions

Conditions	Yield
In gas Irradiation (UV/VIS); in a laser powder synthesis cell; 1330-1530°C; various yields for various conditions; X-ray diffraction; transmission electron microscopy; single point BET surface area analysis; thermal gravimetric analysis; differential thermalanalysis; atomic absorption spectroscopy;	A 50-70 B n/a

...Expand

: 12137-20-1
titanium oxide

A: titanium chloride

B: 7705-07-9
titanium(III) chloride

Conditions

Conditions	Yield
With hydrogenchloride byproducts: H2;	A 10-18 B n/a
With HCl

: 7440-32-6
titanium

A: titanium chloride

B: 7705-07-9
titanium(III) chloride

Conditions

Conditions	Yield
With hydrogenchloride dry HCl gas, room temp., then 350-400°C for 18h;
With hydrogenchloride hot 20% HCl, under H2-stream;	A 0% B n/a
With hydrogenchloride In water byproducts: H2; 300°C;

: 7440-32-6
titanium

: 7550-45-0
titanium tetrachloride

A: titanium chloride

B: 7705-07-9
titanium(III) chloride

Conditions

Conditions	Yield
cooling, in vac., quartz tube, 800-900°C, 24h; 4-5 days, 600-700°C;

...Expand

: Ti7O12

A: 7550-45-0
titanium tetrachloride

B: 7705-07-9
titanium(III) chloride

Conditions

Conditions	Yield
With chlorine

: 75-44-5
phosgene

: (x)Cl3Ti*(x)H2O

: 7782-50-5
chlorine

A: titanium(III) chloride

B: 7705-07-9
titanium(III) chloride

Conditions

Conditions	Yield
hydrolysis, heating in a bomb tube, 120°C;
hydrolysis, heating in a bomb tube, 120°C;

...Expand

: 10294-34-5
boron trichloride

: 7550-45-0
titanium tetrachloride

A: titanium diboride

B: 7705-07-9
titanium(III) chloride

Conditions

Conditions	Yield
With hydrogen In gas byproducts: HCl; Irradiation (UV/VIS); in a laser powder synthesis cell; 1100°C; X-ray diffraction; transmission electron microscopy; single point BET surface area analysis; thermal gravimetric analysis; differential thermalanalysis; atomic absorption spectroscopy;	A 0% B n/a

...Expand

: 96-10-6
diethylaluminium chloride

: 7550-45-0
titanium tetrachloride

: 7705-07-9
titanium(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) TiCl4 and Et2AlCl were reacted, solid was succesively treated with diisopropylether and TiCl4;

: 7550-45-0
titanium tetrachloride

A: titanium nitride

B: 7705-07-9
titanium(III) chloride

Conditions

Conditions	Yield
With nitrogen; hydrogen byproducts: HCl; glowing W-thread, TiCl3 precitipate on the vesselwall, thread temp. 1400-2000 K;
With N2; H2 byproducts: HCl; glowing W-thread, TiCl3 precitipate on the vesselwall, thread temp. 1400-2000 K;

: 7550-45-0
titanium tetrachloride

A: titanium chloride

B: 7705-07-9
titanium(III) chloride

Conditions

Conditions	Yield
In not given Electrolysis;	A 0% B n/a

: 627-44-1
diethylmercury

: 7550-45-0
titanium tetrachloride

: 7705-07-9
titanium(III) chloride

: sodium dithionite

: 7550-45-0
titanium tetrachloride

A: 7446-09-5
sulfur dioxide

B: 7705-07-9
titanium(III) chloride

C: 7647-14-5
sodium chloride

Conditions

Conditions	Yield
In water reaction of TiCl4 with aq. Na2S2O4 forming TiCl3, NaCl and SO2; equilibrium reaction; forward reaction preferenced in an acidic soln. with an excess of Na2S2O4; reverse reaction preferenced in an alkaline soln.;;
In water reaction of TiCl4 with aq. Na2S2O4 forming TiCl3, NaCl and SO2; equilibrium reaction; forward reaction preferenced in an acidic soln. with an excess of Na2S2O4; reverse reaction preferenced in an alkaline soln.;;

...Expand

: titanium chloride

: 7550-45-0
titanium tetrachloride

: 7705-07-9
titanium(III) chloride

: titanium(III) hydroxide

: 7705-07-9
titanium(III) chloride

Conditions

Conditions	Yield
In not given Electrolysis;

: 60644-92-0
2,2-bis(trifluoromethyl)-4,5-dichloro-4,5-difluoro-1,3-dioxolane

: 7705-07-9
titanium(III) chloride

: perfluoro(2,2-dimethyl-1,3-dioxole)

Conditions

Conditions	Yield
In tetrahydrofuran	100%
TiCl3 In tetrahydrofuran

: 6389-79-3
methyl methylphenylphosphinate

: 7705-07-9
titanium(III) chloride

: poly(titanium methylphenylphosphinate)

Conditions

Conditions	Yield
In further solvent(s) byproducts: MeCl; slow heating in neat Ph(Me)P(O)OMe until complete pptn.; particle size and polymerization degree depending on heating rate;	100%

: 83877-23-0
tricyclo[5.2.1.0(2,6)]deca-2,4-dien-6-yllithium

: 7705-07-9
titanium(III) chloride

A: exo,endo-bis(η5-tricyclo{5.2.1.0(2,6)}deca-2,5-dien-4-yl)titanium dichloride

B: exo,exo-bis(η5-tricyclo{5.2.1.0(2,6)}deca-2,5-dien-4-yl)titanium dichloride

C: endo,endo-bis(η(5)-isodicyclopentadienyl)titanium dichloride

Conditions

Conditions	Yield
In tetrahydrofuran (Ar), added at -78°C, temp. quickly increased to 25°C, stirred for 14 h; treated with hydrochloric acid, extracted with chloroform, dried, evapd., recrystd. from dichloromethane/hexane;	A 2% B 98% C n/a

...Expand

: 123-91-1
1,4-dioxane

: 700-58-3
2-Adamantanone

: 7705-07-9
titanium(III) chloride

: 30541-56-1
adamantylidene-adamantane

Conditions

Conditions	Yield
TiCl3 In argon	97%

...Expand

: 7719-09-7
thionyl chloride

: 7705-07-9
titanium(III) chloride

: 21050-13-5
bis(triphenylphosphine)iminium chloride

: bis[bis(triphenylphosphanyl)iminium] hexachlorotitanate(IV)

Conditions

Conditions	Yield
In thionyl chloride (Ar), TiCl3 and ligand mixed (Ti:L=0.64:1.29), slowly treated with SOCl2under stirring, stirred for 4 h at room temp.; pptd.(pentane), filtered, washed (pentane), dried (vac.) for 3 h, elem. anal.;	96%

...Expand

: 7705-07-9
titanium(III) chloride

: 502-42-1
cycloheptanone

: 51175-34-9
cycloheptylidenecycloheptane

Conditions

Conditions	Yield
In tetrahydrofuran	95%

: tetrachloro(η-cyclopentadienyl)molybdenum

: 7705-07-9
titanium(III) chloride

: cyclopentadienyltrichloromolybdenum(IV)

Conditions

Conditions	Yield
In tetrahydrofuran; dichloromethane byproducts: TiCl4; under N2 or Ar; TiCl3 soln. was added to a stirred slurry of equimolar amt. of CpMoCl4; pptn. over 1-2 min, filtered;; the ppt. was washed with CH2Cl2 and dried in vac.; elem. anal.;;	95%

: 680-31-9
N,N,N,N,N,N-hexamethylphosphoric triamide

: 7705-07-9
titanium(III) chloride

: 76077-69-5
TiCl3(((CH3)2N)3PO)3

Conditions

Conditions	Yield
In tetrahydrofuran (N2), TiCl3 extracted into dry THF, organic compound added; collected, washed with n-hexane, pumped in vac. at room temp. for several hours; elem. anal.;	95%

: niobium

: thallium chloride

: 10026-12-7
niobium pentachloride

: 7705-07-9
titanium(III) chloride

: Tl(1+)*Ti(3+)*Nb6Cl18(4-)=TlTi[Nb6Cl18]

Conditions

Conditions	Yield
In neat (no solvent, solid phase) byproducts: Nb3Cl8; Ar atmosphere, TlCl, TiCl3, Nb, NbCl5 in sealed quartz tube at 720 °C for 3 d, heating and cooling rates: 50 °/h;	95%

...Expand

: niobium

: rubidium chloride

: 10026-12-7
niobium pentachloride

: 7705-07-9
titanium(III) chloride

: Rb(1+)*Ti(3+)*Nb6Cl18(4-)=RbTi[Nb6Cl18]

Conditions

Conditions	Yield
In neat (no solvent, solid phase) byproducts: Nb3Cl8; Ar atmosphere, RbCl, TiCl3, Nb, NbCl5 in sealed quartz tube at 720 °C for 3 d, heating and cooling rates: 50 °/h;	95%

...Expand

: niobium

: potassium chloride

: 10026-12-7
niobium pentachloride

: 7705-07-9
titanium(III) chloride

: K(1+)*Ti(3+)*Nb6Cl18(4-)=KTi[Nb6Cl18]

Conditions

Conditions	Yield
In neat (no solvent, solid phase) byproducts: Nb3Cl8; Ar atmosphere, KCl, TiCl3, Nb, NbCl5 in sealed quartz tube at 720 °C for 3 d, heating and cooling rates: 50 °/h;	95%

...Expand

: niobium

: indium chloride

: 10026-12-7
niobium pentachloride

: 7705-07-9
titanium(III) chloride

: In(1+)*Ti(3+)*Nb6Cl18(4-)=InTi[Nb6Cl18]

Conditions

Conditions	Yield
In neat (no solvent, solid phase) byproducts: Nb3Cl8; Ar atmosphere, InCl, TiCl3, Nb, NbCl5 in sealed quartz tube at 720 °C for 3 d, heating and cooling rates: 50 °/h;	95%

...Expand

: niobium

: cesium chloride

: 10026-12-7
niobium pentachloride

: 7705-07-9
titanium(III) chloride

: Cs(1+)*Ti(3+)*Nb6Cl18(4-)=CsTi[Nb6Cl18]

Conditions

Conditions	Yield
In neat (no solvent, solid phase) byproducts: Nb3Cl8; Ar atmosphere, CsCl, TiCl3, Nb, NbCl5 in sealed quartz tube at 720 °C for 3 d, heating and cooling rates: 50 °/h;	95%

...Expand

: 3-(methoxycarbonylhydrazono)-2-(3-nitrophenylamino)butyric acid ethyl ester

: 7705-07-9
titanium(III) chloride

: 946130-11-6
2-(3-nitrophenylamino)-3-oxobutanoic acid ethyl ester

Conditions

Conditions	Yield
In hydrogenchloride; water; ethyl acetate; acetone	95%

: 7719-09-7
thionyl chloride

: 13499-05-3
hafnium tetrachloride

: 7705-07-9
titanium(III) chloride

: 21050-13-5
bis(triphenylphosphine)iminium chloride

: di[bis(triphenylphosphanyl)iminium] decachloridohafnatetitanate

Conditions

Conditions	Yield
In neat (no solvent) (Ar), HfCl4, TiCl3, bis(triphenylphosphanyl)iminium chloride (1:1:2) treated dropwise under stirring with SOCl2, refluxed for 1 h, cooled to room temp., stirred for 2 h; concd.(vac.), pptd.(pentane), filtered, washed (pentane), dried (vac.) for 2 h, elem. anal.;	94%

...Expand

: 7719-09-7
thionyl chloride

: 56-37-1
N-benzyl-N,N,N-triethylammonium chloride

: 13499-05-3
hafnium tetrachloride

: 7705-07-9
titanium(III) chloride

: di[triethylbenzylammonium] decachloridohafnatetitanate

Conditions

Conditions	Yield
In neat (no solvent) (Ar), HfCl4, TiCl3, (Et3NBz)Cl (1:1:2) treated dropwise under stirring with SOCl2, refluxed for 1 h, cooled to room temp., stirred for 2 h; concd.(vac.), pptd.(pentane), filtered, washed (pentane), dried (vac.) for 2 h, elem. anal.;	94%

...Expand

: 7719-09-7
thionyl chloride

: 7705-07-9
titanium(III) chloride

: 21050-13-5
bis(triphenylphosphine)iminium chloride

: tris[bis(triphenylphosphanyl)iminium] Ti2Cl11

Conditions

Conditions	Yield
In thionyl chloride (Ar), TiCl3 and ligand mixed (Ti:L=0.73:1.09), slowly treated with SOCl2under stirring, stirred for 4 h at room temp.; pptd.(pentane), filtered, washed (pentane), dried (vac.) for 3 h, elem. anal.;	93%

...Expand

: 1-methylsulfinyl-1-methylthio-2-[o-(N-crotyl-2,6-dichloroanilino)phenyl]ethylene

: 7705-07-9
titanium(III) chloride

: 1,1-bis(methylthio)-2-[o-(N-crotyl-2,6-dichloroanilino)phenyl]ethylene

Conditions

Conditions	Yield
In chloroform; water; argon	92%

: 109-99-9
tetrahydrofuran

: 7705-07-9
titanium(III) chloride

: titanium(III) chloride tetrahydrofuran

Conditions

Conditions	Yield
In tetrahydrofuran the mixt. was refluxed for 22 h, ccoled to room temp. (Ar); ppt. was washed with pentane;	92%

: 7705-07-9
titanium(III) chloride

: 96556-05-7
N,N',N''-trimethyl-1,4,7-triazacyclononane

: {N(CH3)CH2CH2N(CH3)CH2CH2N(CH3)CH2CH2}*Ti(3+)*3Cl(1-)={N(CH3)CH2CH2N(CH3)CH2CH2N(CH3)CH2CH2}TiCl3

Conditions

Conditions	Yield
In acetonitrile Under Ar, dissolving of TiCl3 under reflux, dropwise addn. of triazacyclononane, stirring (30 min, 20°C).; Filtn.;	92%

: 7705-07-9
titanium(III) chloride

: 96556-05-7
N,N',N''-trimethyl-1,4,7-triazacyclononane

: 143144-83-6
TiCl3(C6H12N3(CH3)3)

Conditions

Conditions	Yield
In acetonitrile Ar-purged soln. of TiCl3 in CH3CN refluxed for 30 min, cooled to room temp., dropwise addn. of ligand in CH3CN, stirred at 20°C for 30 min under Ar, blue pptn.; filtered, washed with dry Et2O, air dried; elem. anal.;	92%

: 7647-01-0
hydrogenchloride

: 1,2-bis(hydrindacenyl)benzene, dilithium salt

: 7705-07-9
titanium(III) chloride

: (1,2-bis(hydrindacenyl)benzene)dichlorotitanium

Conditions

Conditions	Yield
In tetrahydrofuran Ar-atmosphere; mixing indene derivative and slight excess of TiCl3, cooling to -78°C, dropwise addn. of THF, warming to room temp., refluxing for 4 h; concn. (vac.), extn. into CHCl3, addn. of 6 M HCl, stirring for 1 h, extn. of water layer with CH2Cl2, drying (MgSO4), concn.; isomer mixt. (dl:meso=1:1) not sepd., detd. by (1)H- and (13)C-NMR spectroscopy;	92%

...Expand

: 288385-99-9
1-(2-fluoro-3-methoxy-6-nitrophenyl)propan-2-one

aqueous ammonium acetate: aqueous ammonium acetate

: 7705-07-9
titanium(III) chloride

: 288385-93-3
2-methyl-4-fluoro-5-methoxy-1H-indole

Conditions

Conditions	Yield
In water; acetone	90%
In water; acetone	90%

...Expand

: 125050-57-9
C5(CH3)4P(C6H5)2Li

: 7705-07-9
titanium(III) chloride

: bis{η5-(diphenylphosphino)tetramethylcyclopentadienyl}dichlorotitanium(IV)

Conditions

Conditions	Yield
In tetrahydrofuran Ar atmosphere; addn. of org. ligand soln. to stirred suspn. of TiCl3; refluxing overnight; solvent removal (vac.); toluene addn. to residue; ppt. removal (filtration, frit, vac.-line); CCl4 addn. to filtrate; stirring (room temp., 1 h); solvent evapn. (reduced pressure); residue washing (pentane); elem. anal.;	90%

: 366-18-7
[2,2]bipyridinyl

: 7705-07-9
titanium(III) chloride

: 22143-19-7
tris-bipyridyl-(2,2') titanium (0)

Conditions

Conditions	Yield
With sodium amalgam In tetrahydrofuran under oxygen-free nitrogen or argon or vac.; 2,2'-bpyridin was added toa suspn. of TiCl3 and sodium amalgam in THF; after stirring for 24 h atroom temp. and filtering, the soln. was reduced under vac.; diethylether was slowly added; ppt. was collected, washed with petroleum (b.p.40-60°C) and recrystd. from THF-diethylether;	89%
With Li In tetrahydrofuran all operations under N2 and Ar atm.; TiCl3 reacted with 3 equiv. amt. ofbipy and excess of Li in THF; purity checked by elem. anal., 1H and 13C NMR spectra;

: 7647-01-0
hydrogenchloride

: 7705-07-9
titanium(III) chloride

: 215949-16-9
1,2-bis(1-indenyl)benzene

: 168642-16-8, 168752-98-5
(1,2-bis(1-indenyl)benzene)dichlorotitanium

Conditions

Yield

With N-BuLi In tetrahydrofuran; hexane N2-atmosphere; addn. of excess BuLi (in hexanes) to indene derivative (in THF) at -78°C, addn. to TiCl3 (in THF) at -78°C, warmingto room temp., refluxing for 6 h, concn., extn. into CHCl3, stirring wi th 6 M HCl for 1.5 h; extn. of water layer with CH2Cl2, drying (MgSO4), concn., filtration, washing (hexanes), drying (vac.); isomer mixt. (dl:meso=1:1) not sepd., detd. by (1)H- and (13)C-NMR spectroscopy;

89%

...Expand

: 1'-acetyl-3,4-dihydro-5-methoxy-6-nitro-spiro[2H-1-benzopyran-2,4'-piperidine]-4-one

: 7705-07-9
titanium(III) chloride

: 144-55-8
sodium hydrogencarbonate

: 124-63-0
methanesulfonyl chloride

: 1'-Acetyl-3,4-dihydro-5-methoxy-6-methanesulfonamido-spiro[2H-1-benzopyran-2,4'-piperidine]-4-one

Conditions

Conditions	Yield
With pyridine In HCl-H2 O; dichloromethane; acetic acid; ethyl acetate	88%

...Expand

: 7719-09-7
thionyl chloride

: 56-37-1
N-benzyl-N,N,N-triethylammonium chloride

: 7705-07-9
titanium(III) chloride

: bis[bis(triphenylphosphanyl)iminium] decachlorodititanate(IV)

Conditions

Conditions	Yield
In thionyl chloride (Ar), TiCl3 and ligand mixed (Ti:L=1.24:1.25), slowly treated with SOCl2under stirring, stirred for 4 h at room temp.; pptd.(pentane), filtered, washed (pentane), dried (vac.) for 3 h, elem. anal.;	88%

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: 571145-97-6
(CH3C5H3NNHC6H3CH3)2

: 7705-07-9
titanium(III) chloride

: lead(II) chloride

: [((CH3C5H3NNC6H3CH3)2)TiCl2]

Conditions

Conditions	Yield
With KH In tetrahydrofuran (Ar); using Schlenk techniques; stirring of soln. of (MeC5H3NNHC6H3Me)2 and KH in THF for 12 h; filtration, addn. to soln. of TiCl3 in toluene at -60°C; warming to room temp., stirring for 12 h, filtration, addn. of PbCl2, stirring for 15 h; concn., extn. with toluene, filtration, concn., washing with pentane, drying under reduced pressure;	87%

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: 7705-07-9
titanium(III) chloride

: 21050-13-5
bis(triphenylphosphine)iminium chloride

: 848826-84-6
bis[bis(triphenylphosphanyl)iminium] ennachlorodititanate(IV)

Conditions

Conditions	Yield
In thionyl chloride (Ar), TiCl3 and ligand mixed (Ti:L=3.67:1.83), slowly treated with SOCl2under stirring, stirred for 4 h at room temp.; pptd.(pentane), filtered, washed (pentane), dried (vac.), elem. anal.;	87%

Titanous chloride Chemical Properties

Molecular Struture:

Molecular Formula: TiCl₃
Molecular Weight: 154.23
IUPAC Name: Trichlorotitanium
Synonyms Titanium chloride (CAS NO.7705-07-9): Titanium(III) chloride
CAS Registry Number: 7705-07-9
EINECS: 231-728-9
Enthalpy of Vaporization: 16.15 kJ/mol
Vapour Pressure: 33900 mmHg at 25°C
Density : 1.2
Melting point: -24 ºC
Boiling point: 100 ºC
Water solubility : Soluble
Product Categories: Inorganics
Mol File: 7705-07-9.mol
Merck : 14,9481
Appearance: Titanium chloride (CAS NO.7705-07-9) is purple crystalline solid.
Stability: Stable, but reacts violently with water and is spontaneously flammable in air.

Titanous chloride Production

Aluminum reduction method using an excessive amount of titanium tetrachloride and aluminum powder at 136 ℃ to react, using aluminum chloride as the initiator generates three titanium tetrachloride and aluminum trichloride. Heated, steam out of an excessive amount of titanium tetrachloride, recovery can be recycled. While Titanium chloride (CAS NO.7705-07-9) can be derived by sublimation of aluminum trichloride .
3TiCl₄ + Al → 3TiCl₃ + A1C1₃

Titanous chloride Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
hamster	LD50	oral	8800mg/kg (8800mg/kg)		Food & Drug Research Laboratories, Inc., Papers. Vol. 124, Pg. -, 1976.
mouse	LD50	oral	10gm/kg (10000mg/kg)		Food & Drug Research Laboratories, Inc., Papers. Vol. 124, Pg. -, 1976.
rabbit	LD50	oral	7200mg/kg (7200mg/kg)		Food & Drug Research Laboratories, Inc., Papers. Vol. 124, Pg. -, 1976.
rat	LD50	oral	10200mg/kg (10200mg/kg)	BEHAVIORAL: ATAXIA KIDNEY, URETER, AND BLADDER: URINE VOLUME INCREASED	Journal of the American College of Toxicology. Vol. 6(1), Pg. 1, 1987.

Titanous chloride Consensus Reports

Reported in EPA TSCA Inventory.

Titanous chloride Safety Profile

Hazard Codes: C,F
Risk Statements: 34-37-35-17-14
14: Reacts violently with water
17: Spontaneously flammable in air
34: Titanium chloride (CAS NO.7705-07-9) can causes burns
35: Causes severe burns
37: Irritating to the respiratory system
Safety Statements: 6-26-30-36/37/39-43-45
6: Keep under ... (inert gas to be specified by the manufacturer)
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
30: Never add water to this product
43: In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add - Never use water)
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
36/37/39: Wear suitable protective clothing, gloves and eye/face protection
RIDADR: UN 3264 8/PG 2
WGK Germany: 3
RTECS: XR1924000
F: 10-23
HazardClass: 8
PackingGroup: II

Titanous chloride Standards and Recommendations

DOT Classification: 8; Label: Corrosive (UN 2869); DOT Class: 4.2; Label: Spontaneously Combustible, Corrosive (UN 2441)

Titanous chloride Specification

1.General Description: A dark violet crystalline solid. Denser than water. Contact may burn skin, eyes, and mucous membranes. May be toxic by ingestion, inhalation and skin absorption. Used to make other chemicals.
2.Air & Water Reactions :Pyrophoric, very reactive with water and moisture in air produces hydrochloric acid, Ignites spontaneously on contact with air; decomposed by water and water vapor forming HCl. Reactivity Profile Acidic salts, such as Titanium chloride (CAS NO.7705-07-9) , are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions. Ethylene can polymerize at low pressure if catalyzed by titanium halides.
4.Health Hazard Fire will produce irritating, corrosive and/or toxic gases. Inhalation of decomposition products may cause severe injury or death. Contact with substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution.
5.Fire Hazard Flammable/combustible material. May ignite on contact with moist air or moisture. May burn rapidly with flare-burning effect. Some react vigorously or explosively on contact with water. Some may decompose explosively when heated or involved in a fire. May re-ignite after fire is extinguished. Runoff may create fire or explosion hazard. Containers may explode when heated.

Product Name

Titanous chloride

Synthetic route

Titanous chloride Chemical Properties

Titanous chloride Production

Titanous chloride Toxicity Data With Reference

Titanous chloride Consensus Reports

Titanous chloride Safety Profile

Titanous chloride Standards and Recommendations

Titanous chloride Specification

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