Tin tetrachloride supplier | CasNO.7646-78-8

Name
Tin tetrachloride
EINECS 231-588-9
CAS No. 7646-78-8
Article Data418
CAS DataBase
Density 2.226
Solubility Completely miscible with water
Melting Point -33 °C(lit.)
Formula Cl₄Sn
Boiling Point 114.1 °C at 760 mmHg
Molecular Weight 260.522
Flash Point 34°F
Transport Information UN 3264 8/PG 2
Appearance Clear to slightly yellow fuming liquid
Safety 26-45-61-7/8-36/37-24/25-23-36/37/39-16
Risk Codes 34-52/53-40-23/24/25-11
Molecular Structure
Hazard Symbols C,T,F
Synonyms Tinchloride (SnCl4) (8CI);Libavius Fuming spirit;NSC 209802;Stannic chloride;Stannic tetrachloride;Tetrachlorostannane;Tetrachlorotin;Tin(IV) chloride;Tin(IV) tetrachloride;Tin Tetrachloride TTC;
PSA 0.00000
LogP 2.37720

Synthetic route

: 13445-49-3
Marshall's acid

: tin(ll) chloride

A: 7664-93-9
sulfuric acid

B: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
In hydrogenchloride room temp.; 10-15 min.;	A n/a B 99%
In hydrogenchloride room temp.; 10-15 min.;	A n/a B 99%

...Expand

: tin(IV) oxide

: iron(II) chloride

: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
With pyrographite In neat (no solvent) byproducts: FeO; heating of a mixture of SnO2 with double excess of FeCl2 forms 98.97 % SnCl4 at 800°C in presence of C;;	98.97%
In neat (no solvent) byproducts: FeO; heating of a mixture of SnO2 with double excess of FeCl2 forms 76.10 % SnCl4 at 800°C;;	76.1%
In neat (no solvent) byproducts: FeO; heating of a mixture of SnO2 with double excess of FeCl2 forms 27.20 % SnCl4 at 700°C; equilibrium reaction discussed;;	27.2%

: tin(IV) oxide

: 7786-30-3
magnesium chloride

: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
With pyrographite In neat (no solvent) byproducts: MgO; heating of a mixture of SnO2 with double excess of MgCl2 forms 98.3 % SnCl4 at 800°C in presence of C;;	98.3%
In neat (no solvent) byproducts: MgO; heating of a mixture of SnO2 with double excess of MgCl2 forms 74.60 % SnCl4 at 800°C;;	74.6%
In neat (no solvent) byproducts: MgO; heating of a mixture of SnO2 with double excess of MgCl2 forms 58.79 % SnCl4 at 700°C; equilibrium reaction examinated;;	58.79%

: tin(IV) oxide

: 7646-85-7
zinc(II) chloride

: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
With pyrographite In neat (no solvent) byproducts: ZnO; heating of a mixture of SnO2 with double excess of ZnCl2 forms 97.87 % SnCl4 at 800°C in presence of C;;	97.87%
In neat (no solvent) byproducts: ZnO; heating of a mixture of SnO2 with double excess of ZnCl2 forms 5.2 % SnCl4 at 800°C;;	5.2%
In neat (no solvent) byproducts: ZnO; heating of a mixture of SnO2 with double excess of ZnCl2 forms 4.3 % SnCl4 at 600°C;;	4.3%

: 117440-15-0
tetrakis-biphenyl-(2)-tin(IV)

A: 10271-66-6
biphenyl-(2)-mercury(II) chloride

B: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
With mercury dichloride In ethanol 20h heating in sealed tube to 120°C; absol. ethanol;;	A 90.5% B n/a
With HgCl2 In ethanol 20h heating in sealed tube to 120°C; absol. ethanol;;	A 90.5% B n/a

: 625-58-1
ethyl nitrate

: tin(ll) chloride

A: 5470-11-1
hydroxylamine hydrochloride

B: 7664-41-7
ammonia

C: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
With hydrogenchloride In hydrogenchloride byproducts: C2H5OH, H2O; in concd. HCl soln.; evapn. of the alcohol,diluting with water,pptg. of the Sn with H2S,evapn. and crystn. from alcohol;	A 90% B <1 C n/a

...Expand

: 56-23-5
tetrachloromethane

: 595-90-4
tetraphenyltin(IV)

: 94-36-0
dibenzoyl peroxide

A: 67-72-1
hexachloroethane

B: 7646-78-8
tin(IV) chloride

C: 108-90-7
chlorobenzene

D: 88-99-3
benzene-1,2-dicarboxylic acid

E: 65-85-0
benzoic acid

Conditions

Conditions	Yield
50h boiling;	A n/a B 84.1% C n/a D n/a E n/a

...Expand

: Tc(dimethylglyoxime)3(μ-OH)SnCl3*H2O

A: TcCl(dimethylglyoxime)3

B: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
With HCl In acetonitrile room temp., 30 min. (crystn.); cooling (-20°C), decantation, washing (cold MeCN, cold 1 M HCl), drying (vac., 6 h), recrystn. (EtOH/HCl); elem. anal.;	A 82% B n/a

: (R,R,S,S)-2,2',6,6'-tetra-tert-butyl-4,4'-spirobis(8-sila-4-stannatetrahydro-s-indacene)

: 10026-11-6
zirconium(IV) chloride

: rac-dimethylsilanediylbis(t-butylcyclopentadienyl) zirconium dichloride

B: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
In toluene stirring (16 h); solvent removal (vac.), addn. pentane, filtration, volatiles rremoval (vac.);	A 80% B n/a

...Expand

: Tc(cyclohexanedione dioxime)3(μ-OH)SnCl3*3H2O

A: TcCl(cyclohexanedione dioxime)3

B: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
With HCl In acetonitrile stirring (30 min., pptn.); addn. of excess 1 M HCl, collection (after 15 min.), washing (1 M HCl, H2O), drying (vac.), recrystn. (MeCN/1 M HCl); elem. anal.;	A 75% B n/a

: 10170-69-1
dimanganese decacarbonyl

: tin(ll) chloride

A: {Mn(CO)4SnCl((CH3)2NCHO)}3

B: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
In N,N-dimethyl-formamide byproducts: CO; Ar atmosphere, 150°C, 24 h; pptn. on addn. of H2O, washing (dild. HCl and cyclohexane), drying (vac.); elem. anal.;	A 73% B n/a

...Expand

: 625-01-4
ethyl chlorosulfate

: 7553-56-2
iodine

tin: tin

A: 7647-01-0
hydrogenchloride

B: 74-85-1
ethene

C: 7646-78-8
tin(IV) chloride

D SO2: SO2

Conditions

Conditions	Yield
at 130℃;

...Expand

: (4-ethoxycarbonyl-3,5-dimethyl-pyrrol-2-yl)-(4-ethoxycarbonyl-3,5-dimethyl-pyrrol-2-ylidene)-methane; compound with tin tetrachloride

: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
beim Erhitzen;

: tin(IV) chloride * 2 ether

A: 60-29-7
diethyl ether

B: 7646-78-8
tin(IV) chloride

: tin(IV) chloride * 2 ether

A: 60-29-7
diethyl ether

B: 75-00-3
chloroethane

C: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
bei hoeherer Temperatur;

...Expand

: 64-17-5
ethanol

: 595-90-4
tetraphenyltin(IV)

mercury (II)-chloride: mercury (II)-chloride

A: 7646-78-8
tin(IV) chloride

B: 100-56-1
phenylmercury(II) chloride

...Expand

: diisopentyl ether ; compound with tin tetrachloride

A: 7646-78-8
tin(IV) chloride

B di-g-pentyl ether: di-g-pentyl ether

Conditions

Conditions	Yield
bei der Destillation;

: 625836-84-2
4-benzylmercapto-3-nitro-1,8-naphthalic anhydride

A: 625836-85-3
4-benzylmercapto-3-amino-1,8-naphthalic anhydride

B: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
With hydrogenchloride; tin(ll) chloride In water at 90℃; for 2h;

: 69080-31-5
tin tetrachloride pyridine adduct

A: 110-86-1
pyridine

B: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
thermal dissociation, 280 to 340°C; reaction monitoring by pressure measurement;

: ammonium chloride

: tin(IV) oxide

: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
In neat (no solvent) calcination of SnO2 and NH4Cl;;

: 10028-15-6
ozone

: tin(ll) chloride

A: 7732-18-5
water

B: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
With hydrogenchloride; oxygen In not given redn. of O3 by SnCl2 in a HCl-containing soln. by shaking in a O2-O3 mixture for a period of 90 min.;;

...Expand

: iron(III) oxide

: 7782-50-5
chlorine

: tin(IV) oxide

A: 7705-08-0
iron(III) chloride

B: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
Kinetics; chlorination of mechanical SnO2/Fe2O3 mixt. at const. temp. in range 700-850°C; monitoring by gravimetric and chem. anal.; X-ray diffraction;
Kinetics; chlorination of SnO2/Fe2O3 mixt. (obtained by copptn. from hydrochloric SnCl4/FeCl3 soln. with concd. ammonia and ppt. calcination in air at 600°C for 24 h) at const. temp. in range 700-850°C; monitoring by gravimetric and chem. anal.; X-ray diffraction;

...Expand

: indium(III) oxide

: 7782-50-5
chlorine

: tin(IV) oxide

A: 27693-84-1, 21563-01-9
In2Cl6

B: 10025-82-8
indium(III) chloride

C: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
In neat (no solvent) Kinetics; byproducts: O2; chlorination of equimolar mixt. of In2O3/SnO2 at const. temp. in range 500-700°C (Cl2 flow 100 ml/min); chem. anal.;
With sulfur dioxide In neat (no solvent) Kinetics; byproducts: O2, SO3, In2(SO4)3; chlorination of equimolar mixt. of In2O3/SnO2 at const. temp. in range 500-700°C (Cl2/SO2 flow 100 ml/min); chem. anal.;

...Expand

: tin (IV) chloride pentahydrate

: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
With SOCl2 or COCl2 In neat (no solvent)
With COCl2 In neat (no solvent) complete draining with COCl2 at 100°C in 24 h;;
With thionyl chloride In neat (no solvent) complete draining with boiling SOCl2 in some hours;;

: 165071-88-5
4-[N-ethyl,N-(2-chloroethyl)amino]nitrobenzene

: 7646-78-8
tin(IV) chloride

: 32868-99-8
4-[N-ethyl,N-(2-chloroethyl)amino]aniline hydrochloride

Conditions

Conditions	Yield
With ammonium hydroxide In 1,4-dioxane; hydrogenchloride	100%

: 7646-78-8
tin(IV) chloride

: Dimethylaluminium-acetylacetonat

: 594-27-4
tetramethylstannane

Conditions

Conditions	Yield
In benzene molar ratio 2 : 1, room temp.;	100%
In benzene molar ratio 2 : 1, room temp.;	100%

: 110-91-8
morpholine

: 7646-78-8
tin(IV) chloride

: [SnCl4(morpholine)2]

Conditions

Conditions	Yield
In tetrachloromethane under N2; soln. of SnCl4 in CCl4 mixed with ligand (molar ratio 1:2); stirred for several h; filtered; solid washed with petroleum ether; dried in vac.; stored in desiccator over CaCl2; elem. anal.;	100%

: 110-89-4
piperidine

: 7646-78-8
tin(IV) chloride

: [SnCl4(piperidine)2]

Conditions

Conditions	Yield
In tetrachloromethane under N2; soln. of SnCl4 in CCl4 mixed with ligand (molar ratio 1:2); stirred for several h; filtered; solid washed with petroleum ether; dried in vac.; stored in desiccator over CaCl2; elem. anal.;	100%

: 110-86-1
pyridine

: 7646-78-8
tin(IV) chloride

: [SnCl4(pyridine)2]

Conditions

Conditions	Yield
In tetrachloromethane under N2; soln. of SnCl4 in CCl4 mixed with pyridine (molar ratio 1:2); stirred for several h; filtered; solid washed with petroleum ether; dried in vac.; stored in desiccator over CaCl2; elem. anal.;	100%

: 108-89-4
picoline

: 7646-78-8
tin(IV) chloride

: [SnCl4(γ-picoline)2]

Conditions

Conditions	Yield
In tetrachloromethane under N2; soln. of SnCl4 in CCl4 mixed with ligand (molar ratio 1:2); stirred for several h; filtered; solid washed with petroleum ether; dried in vac.; stored in desiccator over CaCl2; elem. anal.;	100%

: 91-22-5
quinoline

: 7646-78-8
tin(IV) chloride

: [SnCl4(quinoline)1.5]

Conditions

Conditions	Yield
In tetrachloromethane under N2; soln. of SnCl4 in CCl4 mixed with ligand (molar ratio 1:2); stirred for several h; filtered; solid washed with petroleum ether; dried in vac.; stored in desiccator over CaCl2; elem. anal.;	100%

: 366-18-7
[2,2]bipyridinyl

: 7646-78-8
tin(IV) chloride

: [SnCl4(2,2'-bipyridine)]

Conditions

Conditions	Yield
In tetrachloromethane under N2; soln. of SnCl4 in CCl4 mixed with ligand (molar ratio 1:2); stirred for several h; filtered; solid washed with petroleum ether; dried in vac.; stored in desiccator over CaCl2; elem. anal.;	100%

: 7646-78-8
tin(IV) chloride

: 55147-78-9
bis(bis(trimethylsilyl)amido)tin(II)

: 145298-59-5
bis{bis(trimethylsilyl)amino}tin dichloride

Conditions

Conditions	Yield
In hexane byproducts: SnCl2; (N2); SnCl4 added dropwise (vigorous stirring, -78°C); kept for 12 h at room temp.; filtered; hexane removed (vac.);	100%

: 232946-68-8
4-(2-(trimethylgermyl)ethyl)phenol

: 7646-78-8
tin(IV) chloride

: 232946-69-9
HOC6H4(CH2)2Ge(CH3)2Cl

Conditions

Conditions	Yield
In nitromethane heating at 50°C for 6 h;	100%

: 110-85-0
piperazine

: 7646-78-8
tin(IV) chloride

: [SnCl4(piperazine)1.5]

Conditions

Conditions	Yield
In tetrachloromethane under N2; soln. of SnCl4 in CCl4 mixed with ligand (molar ratio 1:2); stirred for several h; filtered; solid washed with petroleum ether; dried in vac.; stored in desiccator over CaCl2; elem. anal.;	100%

: tin tetraacetate

: 7646-78-8
tin(IV) chloride

: tin dichloride diacetate

Conditions

Conditions	Yield
In chloroform absence of moisture; equimolar amts., refluxing (3-4 h); solvent removal (reduced pressure); elem. anal.;	100%

: 7646-78-8
tin(IV) chloride

: 107-19-7
propargyl alcohol

: 1322728-88-0
1-trichlorostannyl-2-chloro-2-hydroxymethyl-ethene

Conditions

Conditions	Yield
In dichloromethane N2; DCM soln. of ligand and SnCl4 (1:1 molar ratio) stirred at room temp. for 24 h; evapd. (vac., room temp.), NMR;	100%
In chloroform-d1 N2; 1:1 mixt. at 25°C; NMR;

: 7646-78-8
tin(IV) chloride

: 693-02-7
hex-1-yne

: 1322728-87-9
1-trichlorostannyl-2-chloro-2-n-butyl-ethene

Conditions

Conditions	Yield
In dichloromethane N2; DCM soln. of ligand and SnCl4 (1:1 molar ratio) stirred at room temp. for 24 h; evapd. (vac., room temp.), NMR;	100%
In chloroform-d1 N2; 1:1 mixt. at 25°C; NMR;

: 917-92-0
2,2-dimethyl-3-butyne

: 7646-78-8
tin(IV) chloride

: 1322728-83-5
1-trichlorostannyl-2-chloro-2-tert-butyl-ethene

Conditions

Conditions	Yield
In dichloromethane N2; DCM soln. of ligand and SnCl4 (1:1 molar ratio) stirred at room temp. for 24 h; evapd. (vac., room temp.), NMR;	100%
In chloroform-d1 N2; 1:1 mixt. at 25°C; NMR;

: 7646-78-8
tin(IV) chloride

: 536-74-3
phenylacetylene

: 1322728-81-3
1-trichlorostannyl-2-chloro-2-phenyl-ethene

Conditions

Conditions	Yield
In dichloromethane N2; DCM soln. of ligand and SnCl4 (1:1 molar ratio) stirred at room temp. for 24 h; evapd. (vac., room temp.), NMR;	100%
In chloroform-d1 N2; 1:1 mixt. at 25°C; NMR;

: ammonium sulfate

: 7646-78-8
tin(IV) chloride

: 7783-05-3
disulfuric acid

: O21S6Sn(2-)*2H4N(1+)

Conditions

Conditions	Yield
at 250℃; for 24h;	100%

...Expand

: 7646-78-8
tin(IV) chloride

: 7783-05-3
disulfuric acid

: silver sulfate

: O21S6Sn(2-)*2Ag(1+)

Conditions

Conditions	Yield
at 250℃; for 24h;	100%

...Expand

: C38H40Sn

: 7646-78-8
tin(IV) chloride

: C36H34Cl2Sn

Conditions

Conditions	Yield
In neat (no solvent) at 130℃; for 14h; Schlenk technique;	100%

: 4885-02-3
Dichloromethyl methyl ether

: C24H28S3

: 7646-78-8
tin(IV) chloride

: C25H27S3(1+)*0.5Cl6Sn(2-)

Conditions

Conditions	Yield
In 1,2-dichloro-ethane for 24h; Reflux; Inert atmosphere;	100%

...Expand

: 7647-01-0
hydrogenchloride

: 7732-18-5
water

: 4-methyl-7-(pyrazin-2-yl)-2H-[1,2,4]triazolo[3,2-c][1,2,4]triazole

: 7646-78-8
tin(IV) chloride

: C8H7N7*Cl6Sn(2-)*2H2O*2H(1+)

Conditions

Conditions	Yield
In ethanol	100%

...Expand

: 75-00-3
chloroethane

: 7646-78-8
tin(IV) chloride

: 597-64-8
tetraethyltin

Conditions

Conditions	Yield
With magnesium In diethyl ether; toluene at 50℃; Inert atmosphere; Flow reactor;	99.4%

: 304-88-1
N-phenylbenzohydroxamic acid

: 7646-78-8
tin(IV) chloride

: dichlorotin bis-N-benzoyl-N-phenylhydroxylamine

Conditions

Conditions	Yield
With Li In methanol (Ar); Li was dissolved in dry MeOH, soln. of hydroxylaminederiv. was added and then SnCl4 was dropped into the stirred mixt.; formed ppt. was filtered off, washed with MeOH and ether, and dried in vac.; recrystn. from MeOH/CHCl3; elem. anal.;	99.3%

: N-[2-Hydroxy-3-nitrophenyl]-N'-[2-bromophenyl] urea

: 7646-78-8
tin(IV) chloride

: 182500-25-0
N-(2-hydroxy-3-aminophenyl)-N'-(2-bromophenyl)urea

Conditions

Conditions	Yield
In ethanol	99%
In ethanol	99%
In ethanol	99%

: 597580-25-1
3-mercaptothietane

: 7646-78-8
tin(IV) chloride

: C16H28S4Sn

Conditions

Conditions	Yield
Stage #1: 3-mercaptothietane With sodium hydroxide In water at 20℃; for 0.666667h; Stage #2: tin(IV) chloride In water at 30℃; for 6h; Product distribution / selectivity;	99%
With pyridine In dichloromethane at -30 - -20℃; for 6.08h; Product distribution / selectivity;	75%

: 594-27-4
tetramethylstannane

: 7646-78-8
tin(IV) chloride

: 1066-45-1
trimethyltin(IV)chloride

Conditions

Conditions	Yield
stirring overnight at 60°F, N2-atmosphere; distd. at 15 Torr;	99%
molar ratio of (CH3)4Sn:SnCl4=3:1; distn.;
In neat (no solvent) react. Me4Sn with SnCl4 (3:1) at 130°C for 2 h; recrystn. from hexane;

: 7646-78-8
tin(IV) chloride

: tin(ll) chloride

Conditions

Conditions	Yield
With triphenyl phosphine In dichloromethane Ar atmosphere; 20°C, 7 d;	99%
In gas byproducts: SnCl; formation with SnCl at flash-light photolysis of gasous SnCl4 with intermediate formation of SnCl3;;
With methane In neat (no solvent) redn. to SnCl2 by use of CH4 in a closed quartz tube above ca. 500°C;;

: 92-66-0
4-bromo-1,1'-biphenyl

: 7646-78-8
tin(IV) chloride

: 39767-03-8
tetra(p-biphenylyl)tin

Conditions

Conditions	Yield
Stage #1: 4-bromo-1,1'-biphenyl With magnesium In tetrahydrofuran; ethylene dibromide for 2h; Reflux; Stage #2: tin(IV) chloride In tetrahydrofuran; ethylene dibromide at 20℃; Reflux;	99%
With Na In benzene addn. of a small portion of p-bromobiphenyl and SnCl4 to sodium in benzene, warmed, dropwise addn. of the remaining portion with stirring over 30 min, refluxed for 5 h; filtered hot, cooled; elem. anal.;	90%
With Na In benzene Wurtz react.;

: 60-35-5
acetamide

: 7646-78-8
tin(IV) chloride

: SnCl4(acetamide)2

Conditions

Conditions	Yield
In Petroleum ether SnCl4 was mixed with soln. of ligand in petroleum ether under N2, stirred for several h; filtered, washed with petroleum ether, recrystd. from dichloroethane, dried in vac.; elem. anal.;	99%

Tin tetrachloride Chemical Properties

Product Name: Tin tetrachloride (CAS NO.7646-78-8)

Molecular Formula: SnC_l4
Molecular Weight: 260.50g/mol
Mol File: 7646-78-8.mol
EINECS: 231-588-9
Appearance: colourless liquid
Melting Point: -33 °C(lit.)
Boiling point: 114.1 °C at 760 mmHg
Storage Temperature: Store at RT.
Water Solubility: reacts
Sensitive: Air Sensitive
Stability: Stability Stable, but may decompose upon exposure to moist air or water. Incompatible with strong bases, alcohols.
Surface Tension:
Enthalpy of Vaporization: 16.15 kJ/mol
Vapour Pressure: 23.9 mmHg at 25°C
H-Bond Donor: 0
H-Bond Acceptor: 0
Structure Descriptors of Tin tetrachloride (CAS NO.7646-78-8):
IUPAC Name: tetrachlorostannane
Canonical SMILES: Cl[Sn](Cl)(Cl)Cl
InChI: InChI=1S/4ClH.Sn/h4*1H;/q;;;;+4/p-4
InChIKey: HPGGPRDJHPYFRM-UHFFFAOYSA-J
Product Categories: Inorganics; Classes of Metal Compounds; Sn (Tin) Compounds; Typical Metal Compounds

Tin tetrachloride Uses

As mordant, reviving colors, dehydrating agent in organic syntheses, stabilizer for colors & perfumes in soap, in dyeing of fabrics, weighting silk, tinning vessels, in ceramics to produce abrasion resistant or light reflecting coatings.

Tin tetrachloride Toxicity Data With Reference

1.		ihl-rat LC50:2300 mg/m3/10M		TOXID9 Toxicologist. 1 (1981),77.
2.		ipr-mus LD50:101 mg/kg		COREAF Comptes Rendus Hebdomadaires des Seances de l’Academie des Sciences. 256 (1963),1043.

Tin tetrachloride Consensus Reports

Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Tin tetrachloride Safety Profile

Poison by intraperitoneal route. Moderately toxic by inhalation. A corrosive irritant to skin, eyes, and mucous membranes. Combustible by chemical reaction. Upon contact with moisture, considerable heat is generated. Violent reaction with K, Na, turpentine, ethylene oxide, alkyl nitrates. Dangerous; hydrochloric acid is liberated on contact with moisture or heat. When heated to decomposition it emits toxic fumes of Cl⁻. See also HYDROCHLORIC ACID.
Safety Information of Tin tetrachloride (CAS NO.7646-78-8):
Hazard Codes C Corrosive ,T Toxic ,F Flammable
Risk Statements: 34-52/53-40-23/24/25-11
R34:Causes burns.
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R40:Limited evidence of a carcinogenic effect.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.
R11:Highly flammable.
Safety Statements: 26-45-61-7/8-36/37-24/25-23-36/37/39-16
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S24/25:Avoid contact with skin and eyes.
S23:Do not breathe vapour.
S36/37:Wear suitable protective clothing and gloves.
S16:Keep away from sources of ignition.
RIDADR: UN 3264 8/PG 2
WGK Germany: 2
RTECS: XP8750000
F: 10-21
TSCA: Yes
HazardClass: 8
PackingGroup: II

Tin tetrachloride Standards and Recommendations

OSHA PEL: TWA 2 mg(Sn)/m³
ACGIH TLV: TWA 2 mg(Sn)/m³
DOT Classification: 8; Label: Corrosive

Tin tetrachloride Specification

Tin tetrachloride , its CAS NO. is 7646-78-8, the synonyms are Etain (tetrachlorure d') ; Libavius fuming spirit ; Stagno (tetracloruro di) ; Stannane, tetrachloro- ; Stannic chloride ; Stannic chloride, anhydrous ; Stannic tetrachloride ; Tetrachlorostannane ; Tetrachlorotin ; Tin Tetrachloride, anhydrous ; Tin chloride, fuming (DOT) ; Tin perchloride ; Tin tetrachloride ; Tin(IV) chloride ; Tin(IV) tetrachloride ; Tintetrachloride .

Product Name

Tin tetrachloride

Synthetic route

Tin tetrachloride Chemical Properties

Tin tetrachloride Uses

Tin tetrachloride Toxicity Data With Reference

Tin tetrachloride Consensus Reports

Tin tetrachloride Safety Profile

Tin tetrachloride Standards and Recommendations

Tin tetrachloride Specification

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