Magnesium chloride supplier

Name
Magnesium chloride
EINECS 232-094-6
CAS No. 7786-30-3
Article Data343
CAS DataBase
Density 2.32 g/mL at 25 °C(lit.)
Solubility 400 g/L (20 °C) in water
Melting Point 714 °C(lit.)
Formula Cl₂Mg
Boiling Point 1412 °C
Molecular Weight 95.211
Flash Point
Transport Information
Appearance white powder
Safety 26-36-24/25-22-36/37-39
Risk Codes 36/37/38-43-36/37
Molecular Structure
Hazard Symbols Xi
Synonyms Magnesiumchloride (6CI,7CI,8CI);Aerotex Accelerator MX;C-TEK;Catalyst G;Ekimac;FIX-Mg;Freecat MX;HMC 23D;Magnesium dichloride;Magnesium(II) chloride;Magnogene;NSC 529832;TMT 2;White Nigari NS;Magnesium chloride anhydrous;
PSA 0.00000
LogP -5.99200

Synthetic route

: Mg(2+)*2Mo(6+)*2Cl(1-)*6O(2-)*4C4H8O=[Mg(ClMoO3)2(C4H8O)4]

A: molybdenum(VI) oxide

B: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In tetrahydrofuran Ar atm.; hot THF;	A 100% B 100%

: 7439-95-4
magnesium

: 7646-85-7
zinc(II) chloride

: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In melt melting the starting materials in an evacuated silica ampoule at 900°C for 48 h, cracking the ampoule under Ar;	95%
In neat (no solvent) reduction of molten ZnCl2 with Mg forming MgCl2;;
In neat (no solvent) reduction of molten ZnCl2 with Mg forming MgCl2;;

: 10026-11-6
zirconium(IV) chloride

: 7439-95-4
magnesium

A: 7440-67-7
zirconium

B: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In melt heating at 800°C under inert gas in a closed vessel, Kroll-process; apparatus described;; separation of Mg and MgCl2 by vacuum destillation;;	A 93% B n/a
In melt heating at 800°C under inert gas in a closed vessel, Kroll-process; apparatus described;; separation of Mg and MgCl2 by vacuum destillation;;	A 93% B n/a

...Expand

: magnesium silicide

: ammonium chloride

: silicon nitride

B: 7664-41-7
ammonia

C: 1333-74-0
hydrogen

D: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In neat (no solvent) High Pressure; mixed, sealed in autoclave under Ar, heated at 450, 500, 550, and 600 °C for 10 h; washed with water, dried in vac. at 70 °C for 12 h; powder XRD;	A 93% B n/a C n/a D n/a

...Expand

: 194354-14-8
dichlorobis(3,5-di-tert-butylpyrazolylato)titanium(IV)

: 676-58-4
methylmagnesium chloride

A: 222026-71-3
dimethylbis(3,5-di-tert-butylpyrazolylato)titanium(IV)

B: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In tetrahydrofuran; hexane Ar-atmosphere; MeMgCl soln. (THF) addn. (0°C), stirring (room temp., 20 h), evapn. (reduced pressure); extg. (hexane), filtering, evapn. (reduced pressure); elem. anal.;	A 93% B n/a

...Expand

: 13170-43-9
(trimethylsilyl)methylmagnesium chloride

: 7721-01-9
tantalum pentachloride

: 594-09-2
trimethylphosphane

: ((CH3)3SiCH2)3Ta(P(CH3)3)(CHSi(CH3)3)

B: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In diethyl ether; hexane under N2 atm. slurry TaCl5 in hexane at -20°C was treated dropwise with Me3SiCH2MgCl in Et2O, solvent was removed in vacuo, residue was taken up in hexane at 0°C and filtered, PMe3 was added and heated to 50°C for 1 h; soln. was filtered, concd. and cooled to -20°C;	A 92% B n/a

...Expand

: 154005-14-8, 141724-21-2, 162429-20-1, 100080-82-8, 112243-78-4
rac-ethanediyl-bis(1-indenyl)zirconium dichloride

: 75-16-1
methylmagnesium bromide

A: rac-ethylenebis(1-indenyl)zirconium dimethyl

B: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In 1,4-dioxane; diethyl ether; hexane (N2); dioxane was added to 3 M soln. MeMgBr in hexane and Et2O, stirred for 1 h, filtered, filtrate was added to soln. of zirconium complex in Et2O at -78°C, warmed to room temp. overnight; evapd., dissolved in benzene, filtered, evapd. in vac., crystd. from toluene/hexanes;	A 91% B n/a

...Expand

: 925-90-6
ethylmagnesium bromide

: palladium dichloride

A: 74-84-0
ethane

B: 74-85-1
ethene

C: 7440-05-3
palladium

D: magnesium bromide

E: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In tetrahydrofuran To a soln. of anhydrous salt is added C2H5MgBr at 20°C with stirring. The reaction mixture is left for 5 - 6 h at room temp.; decantation, washing with THF, water and ethanol; electron diffraction;	A n/a B n/a C 90% D n/a E n/a

...Expand

: 185154-26-1
bis(η5-tetramethyl(trimethylsilyl)cyclopentadienyl)titanium dichloride

: 7439-95-4
magnesium

: 14630-40-1
Bis(trimethylsilyl)ethyne

A: 195259-28-0
(η2-bis(trimethylsilyl)ethyne)bis(η5-tetramethyl(trimethylsilyl)cyclopentadienyl)titanium(II)

B: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In tetrahydrofuran -18°C (40 h), filtering, evapn. (vac.); extg. (hexane), MgCl2 pptn. (-5°C, overnight), concg., crystn. (-18°C, overnight); elem. anal.;	A 80% B n/a

...Expand

: 7440-55-3
gallium

: 7439-95-4
magnesium

: 74-88-4
methyl iodide

A: 7786-30-3
magnesium chloride

B: 1445-79-0
trimethyl gallium

Conditions

Conditions	Yield
In neat (no solvent) inert gas atmosphere; mixing, heating in autoclave (100 - 160°C, stirring, 12 h); distillation;	A n/a B 65%

...Expand

: 7440-55-3
gallium

: 7439-95-4
magnesium

: 75-03-6
ethyl iodide

A: 1115-99-7
triethyl gallium

B: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In hexane inert condition; addn. of hexane to mixt. of Mg and Ga (vac.), addn. of hexane, dropwise addn. of EtI (boiling hexane); distillation;	A 65% B n/a

...Expand

: 7440-55-3
gallium

: 7553-56-2
iodine

: 7439-95-4
magnesium

: 75-03-6
ethyl iodide

A: 1115-99-7
triethyl gallium

B: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In neat (no solvent) inert condition; addn. of I2 to mixt. of Mg and Ga, heating in vac. (150°C), chilling, addn. of EtI (50 - 70°C, 1 h), heating (90 °C, 4 h); distillation;	A 61% B n/a

...Expand

: 245491-72-9
[ZrCl2(C32H38N4)]

: 6928-77-4
dibenzylmagnesium

A: 253689-33-7
C39H45N4Zr(C4H8O)(CH2C6H5)

B: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In tetrahydrofuran; toluene stirring (room temp., 1 h); evapn., toluene addn., filtering, evapn., n-pentane addn., filtering, drying (vac.); elem. anal.;	A 61% B n/a

...Expand

Ga(35),Mg(65) (X%): Ga(35),Mg(65) (X%)

: 7553-56-2
iodine

: 75-03-6
ethyl iodide

A: 1115-99-7
triethyl gallium

B: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In neat (no solvent) inert condition; addn. of I2 to alloy Mg-Ga, heating in vac. (150 °C), chilling, addn. of EtI), heating (85°C, 4 h); distillation;	A 57% B n/a

...Expand

: 222026-71-3
dimethylbis(3,5-di-tert-butylpyrazolylato)titanium(IV)

: 75-64-9
tert-butylamine

A: 222027-39-6, 210816-30-1
chlorotris(3,5-di-tert-butylpyrazolato)titanium(IV)

B: 222027-00-1
(tert-butylimido(chloro)(3,5-di-tert-butylpyrazolato)titanium)2

C: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In hexane byproducts: tert-butylammonium chloride; Ar-atmosphere; stirring (room temp., 16 h); filtering, evapn. (reduced pressure), crystn. (hexane, -15°C, -20°C); elem. anal.;	A 56% B 10% C n/a

...Expand

: 222027-39-6, 210816-30-1
chlorotris(3,5-di-tert-butylpyrazolato)titanium(IV)

: 676-58-4
methylmagnesium chloride

A: 222026-93-9
methyltris(3,5-di-tert-butylpyrazolylato)titanium(IV)

B: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In tetrahydrofuran Ar-atmosphere; MeMgCl soln. (THF) addn. (0°C), stirring (room temp., 20 h), evapn. (reduced pressure); extg. (hexane), filtering, evapn. (reduced pressure); elem. anal.;	A 52% B n/a

...Expand

: 7439-95-4
magnesium

: calcium chloride

A: 1333-74-0
hydrogen

B: 7786-30-3
magnesium chloride

C: calcium hydroxide

Conditions

Conditions	Yield
With water In neat (no solvent) reduction of dry CaCl2 in H2-atmosphere on calcination with Mg; treatment of the reaction-products with H2O under formation of H2;;	A 50% B n/a C n/a
With water In neat (no solvent) reduction of dry CaCl2 in H2-atmosphere on calcination with Mg; treatment of the reaction-products with H2O under formation of H2;;	A 50% B n/a C n/a
With water In neat (no solvent) reduction of dry CaCl2 in CO2-atmosphere on calcination with Mg; treatment of the reaction-products with H2O under formation of H2;;	A 30% B n/a C n/a
With water In neat (no solvent) reduction of dry CaCl2 in CO2-atmosphere on calcination with Mg; treatment of the reaction-products with H2O under formation of H2;;	A 30% B n/a C n/a

...Expand

: 1-chloro-2,3-dimethyl-1,2,3-arsadicarba-closo-dodecaborane(9)

: 1068-55-9
isopropylmagnesium chloride

A: 1-isopropyl-2,3-dimethyl-1,2,3-arsadicarba-closo-dodecaborane(9)

B: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In diethyl ether under Ar, -80°C, molar ratio arsacarbollyl:(CH3)2CHMgCl=4.50:4.44, 1h stirring at room temp.; colorless ppt. is filtered off, solvent removed, extd. with hot hexane, evapd. to dryness, subl. in high vac. at 50°C, elem. anal.;	A 50% B n/a

...Expand

: 131063-11-1, 16997-51-6, 19559-06-9
Vanadium (III) chloride-(tris-tetrahydrofuran)

: 879-06-1
pentafluorophenylmagnesium chloride

A: (C6F5)4V*2C4H8O

B: 25377-37-1, 27790-75-6, 82009-22-1
Tetrakis(pyridin)-dichlorovanadin(II)

C: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In tetrahydrofuran 1 mol of complex was slowly added to an THF soln. of 2 mol RMgCl at -15°C, after 1 h the temp. was raised to room temp. (Ar atm.);; dioxane in Et2O was added, evapd., ppt. was washed with Et2O;;	A 43% B 47% C n/a

...Expand

: 131063-11-1, 16997-51-6, 19559-06-9
Vanadium (III) chloride-(tris-tetrahydrofuran)

: 13170-43-9
(trimethylsilyl)methylmagnesium chloride

A: 25377-37-1, 27790-75-6, 82009-22-1
Tetrakis(pyridin)-dichlorovanadin(II)

B: 41572-08-1
tetrakis(trimethylsilylmethyl)vanadium

C: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In diethyl ether 1 mol of complex was slowly added to an ether soln. of 2 mol RMgCl at -15°C, after 1 h the temp. was raised to room temp. (Ar atm.);; dioxane was added, ppt. was extd. with pentane; elem. anal.;;	A 43% B 45% C n/a

...Expand

: 194354-14-8
dichlorobis(3,5-di-tert-butylpyrazolylato)titanium(IV)

: 6921-34-2
benzylmagnesium chloride

A: 222026-78-0
dibenzylbis(3,5-di-tert-butylpyrazolylato)titanium(IV)

B: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In diethyl ether; toluene Ar-atmosphere; BnMgCl soln. (Et2O) addn. (0°C), stirring (room temp., 16 h), evapn. (reduced pressure); extg. (hexane), filtering, concg. (reduced pressure), crystn. (-20°C, 2 d); elem. anal.;	A 43% B n/a

...Expand

: 222027-44-3
trichloro-(3,5-di-tert-butylpyrazolylato)titanium(IV)

: 676-58-4
methylmagnesium chloride

A: 222026-71-3
dimethylbis(3,5-di-tert-butylpyrazolylato)titanium(IV)

B: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In tetrahydrofuran; hexane Ar-atmosphere; pptn. on mixing reagents (-78°C, 0.25 h), stirring(room temp., 3 h), evapn. (reduced pressure); extg. (hexane), filtering, evapn. (reduced pressure);	A 35% B n/a

...Expand

: 7637-07-2
boron trifluoride

: 10294-34-5
boron trichloride

A: boron

B: 10043-11-5
boron nitride

C: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
700-1000°C; diluterd with N2; washing with HCl at 1000°C;	A n/a B 34% C n/a

...Expand

: 1-chloro-2,3-dimethyl-1,2,3-phosphadicarba-closo-dodecaborane(9)

: 1068-55-9
isopropylmagnesium chloride

A: 1-isopropyl-2,3-dimethyl-1,2,3-phosphadicarba-closo-dodecaborane(9)

B: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In diethyl ether under Ar, -80°C, molar ratio ClP((CH3)2C2B9H9):(CH3)2CHMgCl=1:1, warmed to -20°C; colorless ppt. is filtered off, solvent removed, extd. with hot hexane, evapd. to dryness, subl. in high vac. at room temp., elem. anal.;	A 33% B n/a

...Expand

: brucite

: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
With hydrogenchloride In neat (no solvent) heating of brucite at 383-412 °C in a stream of dry HCl with formation of MgCl2;	10.33%
With HCl In neat (no solvent) heating of brucite at 383-412 °C in a stream of dry HCl with formation of MgCl2;	10.33%

: 2386-64-3
ethylmagnesium chloride

: 993-10-2
methyltrichlorogermane

A: C7H17ClGe

B: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In butyldiglyme; ethyldiglym at 40℃; for 3h;

...Expand

: 1068-55-9
isopropylmagnesium chloride

: 993-10-2
methyltrichlorogermane

A: C4H10Cl2Ge

B: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In butyldiglyme; ethyldiglym at 40℃; for 3h;

...Expand

: 1068-55-9
isopropylmagnesium chloride

: 993-10-2
methyltrichlorogermane

A: C7H17ClGe

B: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In butyldiglyme; ethyldiglym at 40℃; for 3h;

...Expand

: C7H17ClGe

: 1068-55-9
isopropylmagnesium chloride

A: diethylisopropylmethylgermane

B: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In butyldiglyme; ethyldiglym for 1h;

...Expand

: 97-93-8
triethylaluminum

: 62202-86-2
n-butyl-ethylmagnesium

A: 14989-29-8
hydridomagnesium chloride

B: (AlEt3)2*MgEt2

C: 693-04-9
butyl magnesium bromide

D: 2386-64-3
ethylmagnesium chloride

E: 7786-30-3
magnesium chloride

Conditions

Conditions	Yield
In 2-Methylpentane for 4383h; Reactivity;

...Expand

: 56-81-5
glycerol

: 7786-30-3
magnesium chloride

: Mg(2+)*H(1+)*C3H5O3(3-)=C3H6O3Mg

Conditions

Conditions	Yield
With copper In glycerol byproducts: CuCl; Electrolysis; electrolysis of MgCl2 in anhydrous glycerin, copper electrodes, formation of CuCl at the anode and of C3H6O3Mg at the cathode;;	100%
With Cu In glycerol byproducts: CuCl; Electrolysis; electrolysis of MgCl2 in anhydrous glycerin, copper electrodes, formation of CuCl at the anode and of C3H6O3Mg at the cathode;;	100%

: chromium(VI) oxide

: 7786-30-3
magnesium chloride

: magnesium chlorochromate

Conditions

Conditions	Yield
In tetrachloromethane stirred vigorously for 3 d under N2; filtd. or evapn. of solvent under reduced pressure;	99%

: potassium dizirconiumenneaisopropoxide

: zirconium isopropoxide

: 7786-30-3
magnesium chloride

: 164989-80-4
MgCl(Zr2(OC3H7)9)

Conditions

Conditions	Yield
In isopropyl alcohol; benzene byproducts: KCl; reflux (2 h), volatiles removal, stirring (70°C, 10 h), KCl pptn.; filtration, volatiles removal (27°C, red. pressure), pptn., recrystn. (n-hexane/toluene) or volatilization (210°C, 0.01 mmHg); elem. anal.;	99%

...Expand

: potassium dizirconiumenneaisopropoxide

: zirconium isopropoxide

: 7786-30-3
magnesium chloride

: 164989-81-5, 57609-07-1
Mg(Zr2(OC3H7)9)2

Conditions

Conditions	Yield
In isopropyl alcohol; benzene byproducts: KCl; reflux (2 h), volatiles removal, stirring (70°C, 10 h), KCl pptn., filtration, volatiles removal, (27°C, red. pressure), pptn.; volatilization (175°C, 0.1 mmHg) (70%); elem. anal.;	99%

...Expand

: potassium tetraisopropoxyaluminate

: 555-31-7
aluminum isopropoxide

: 7786-30-3
magnesium chloride

: 164989-79-1
Mg(2+)*Cl(1-)*Al(OC3H7)4(1-)=MgCl(Al(OC3H7)4)

Conditions

Conditions	Yield
In isopropyl alcohol; benzene byproducts: KCl; stirring (27°C, 12 h), pptn. (KCl), filtration; volatiles removal (reduced pressure, 27°C), recrystn. (hexane/toluene, -10°C); elem. anal.;	99%

...Expand

: 16940-66-2
sodium tetrahydroborate

: 7664-41-7
ammonia

: 7786-30-3
magnesium chloride

: magnesium borohydride - ammonia (1/6)

Conditions

Conditions	Yield
In diethyl ether under Ar atm. soln. Mg(BH4)2 in Et2O was prepared by react. MgCl2 and NaBH4 (V.N.Konoplev, Zh.Neorg.Khim., 1980, 25 (7), 1737-1740), anhydrous ammonia was passed through soln. at -10°C; react. mixt. was allowed to warm to room temp., volatiles were removed in vacuo; elem. anal.;	99%

...Expand

: 1295-35-8
bis(1,5-cyclooctadiene)nickel (0)

: C42H33FP2Si

: 7786-30-3
magnesium chloride

: C42H33ClNiP2Si

Conditions

Conditions	Yield
In tetrahydrofuran at 20℃; for 1h; Reagent/catalyst; Inert atmosphere; Schlenk technique;	99%

...Expand

: tin(IV) oxide

: 7786-30-3
magnesium chloride

: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
With pyrographite In neat (no solvent) byproducts: MgO; heating of a mixture of SnO2 with double excess of MgCl2 forms 98.3 % SnCl4 at 800°C in presence of C;;	98.3%
In neat (no solvent) byproducts: MgO; heating of a mixture of SnO2 with double excess of MgCl2 forms 74.60 % SnCl4 at 800°C;;	74.6%
In neat (no solvent) byproducts: MgO; heating of a mixture of SnO2 with double excess of MgCl2 forms 58.79 % SnCl4 at 700°C; equilibrium reaction examinated;;	58.79%

: tin(IV) oxide

: 7786-30-3
magnesium chloride

: tin(ll) chloride

Conditions

Conditions	Yield
With pyrographite In neat (no solvent) byproducts: MgO, CO; formation at reaction of SnO2, MgCl2 and C under exclusion of air for 2 h at 800°C;; collecting of formed SnCl2 at 300-330°C in a condensator at exclusion of air;;	98.3%
With C In neat (no solvent) byproducts: MgO, CO; formation at reaction of SnO2, MgCl2 and C under exclusion of air for 2 h at 800°C;; collecting of formed SnCl2 at 300-330°C in a condensator at exclusion of air;;	98.3%
With pyrographite In neat (no solvent) byproducts: MgO, CO; heating of a mixture of SnO2 with double excess of MgCl2 in presence of C in 2 h at 523, 548 and 573°C forms liquid SnCl2; examination of the equilibrium reaction;;

: 1333-74-0
hydrogen

: 7439-95-4
magnesium

: 7786-30-3
magnesium chloride

: 63866-76-2
(HMgCl)2(C4H8O)2

Conditions

Conditions	Yield
With tetrahydrofuran In tetrahydrofuran addn. of soln. of MgCl2 in THF to suspn. of Mg powder and catalyst in THF (under Ar), hydrogenation (H2-pressure 40-60 bar, 0°C, 18 h); centrifugation; not isolated;	96%
With tetrahydrofuran In tetrahydrofuran addn. of soln. of MgCl2 in THF to suspn. of Mg powder and catalyst in THF (under Ar), hydrogenation (H2-pressure 50-70 bar, 0°C, 8 h); centrifugation; not isolated;	59%
With tetrahydrofuran In tetrahydrofuran addn. of soln. of MgCl2 in THF to suspn. of Mg powder and catalyst in THF (under Ar), hydrogenation (H2-pressure 50-70 bar, 25°C, 40 h); centrifugation; not isolated;	41%
With catalyst: TiCl4*2THF/ Mg-anthracene In tetrahydrofuran addn. of soln. of MgCl2 in THF to suspn. of Mg powder and catalyst in THF (under Ar), hydrogenation (H2-pressure 50-70 bar, 0°C, 40 h); centrifugation; not isolated;	22%
With tetrahydrofuran In tetrahydrofuran addn. of soln. of MgCl2 in THF to suspn. of Mg powder and catalyst in THF (under Ar), hydrogenation (H2-pressure 50-70 bar, 60°C, 48 h); centrifugation; not isolated;	15%

...Expand

: Na(1+)*Al(ONC(CH3)2)4(1-)=NaAl(ONC(CH3)2)4

: 7786-30-3
magnesium chloride

: 197501-39-6
Mg[Al(ONC(CH3)2)4]2

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: NaCl; (moisture free); reflux (4 h), NaCl pptn.; filtration, excess solvent removal (red. pressure), crystn., recrystn. (toluene, -20°C); elem anal.;	96%

: 59-92-7
levodopa

: 7786-30-3
magnesium chloride

: Mg(L-3,4-dioxyphenylalanine)2

Conditions

Conditions	Yield
Stage #1: levodopa With potassium tert-butylate In tetrahydrofuran; N,N-dimethyl acetamide for 0.25h; Stage #2: magnesium chloride In tetrahydrofuran; N,N-dimethyl acetamide	96%

: 76-05-1
trifluoroacetic acid

: 7786-30-3
magnesium chloride

: 38482-84-7, 123333-72-2
magnesium(II) 2,2,2-trifluoroacetate

Conditions

Conditions	Yield
at 20 - 100℃; for 1h;	95%

: 7786-30-3
magnesium chloride

: sodium trispyrazolylborate

: bis{hydrotris(pyrazolyl)borato}magnesium

Conditions

Conditions	Yield
In water byproducts: NaCl; Trofimenko, S., J. Am. Chem. Soc., 89 (1967), 3170; crystd. (toluene/CH2Cl2), sublimed (vac.); elem. anal., TGA;	94%

: [Rh(1,10-phenanthroline)(NH3)4](CF3SO3)3

: 2051-10-7
5,6-chrysenedione

: 1310-73-2
sodium hydroxide

: 7786-30-3
magnesium chloride

: [Rh(5,6-chrysenequinone diimmine)(1,10-phenanthroline)(NH3)2]Cl3

Conditions

Conditions	Yield
Stage #1: [Rh(1,10-phenanthroline)(NH3)4](CF3SO3)3; 5,6-chrysenedione; sodium hydroxide In water; acetonitrile Stage #2: magnesium chloride With sephadex QAE anionexchange column	94%

...Expand

: 109-99-9
tetrahydrofuran

: 64770-14-5
tert-butyl acetoacetate sodium salt

: 7786-30-3
magnesium chloride

: C56H94Mg2Na2O20

Conditions

Conditions	Yield
at 20℃; for 72h; Inert atmosphere; Schlenk technique; Glovebox;	94%

...Expand

: 16940-66-2
sodium tetrahydroborate

: 110-71-4
1,2-dimethoxyethane

: 7786-30-3
magnesium chloride

: Mg(2+)*2BH4(1-)*1.5CH3OCH2CH2OCH3=Mg(BH4)2*1.5CH3OCH2CH2OCH3

Conditions

Conditions	Yield
In 1,2-dimethoxyethane mixt. of MgCl2, NaBH4 in DME was stirred for 10 h under inert atm; filtered, washed with DME, solvent was vac. distilled, extd. with CH2Cl2, CH2Cl2 was distilled in vacuo; elem. anal.;	93%
for 7 - 22h; Inert atmosphere; Glovebox; Schlenk technique;	85%

...Expand

: 904693-44-3
2,5‐dihydroxyterephthalate

: 7786-30-3
magnesium chloride

: iron(II) chloride

: C8H4O6(2-)*0.1Fe(2+)*0.9Mg(2+)

Conditions

Conditions	Yield
Stage #1: 2,5‐dihydroxyterephthalate; magnesium chloride; iron(II) chloride In methanol; N,N-dimethyl-formamide at 120℃; for 16h; Stage #2: In N,N-dimethyl-formamide at 120℃; for 9h; Stage #3: In methanol at 60℃;	93%

...Expand

: 610-92-4
2,5-dihydroxy-1,4-benzenedicarboxylic acid

: 7786-30-3
magnesium chloride

: iron(II) chloride

: Fe0.1Mg1.9(2,5-dioxido-1,4-benzenedicarboxylate)

Conditions

Conditions	Yield
In methanol; N,N-dimethyl-formamide at 120℃; for 16h;	93%

...Expand

: 546-68-9
titanium(IV) isopropylate

: 7786-30-3
magnesium chloride

: 1126433-59-7
Mg2Ti4Cl4(OCH(CH3)2)16

Conditions

Conditions	Yield
In benzene soln. of Ti(OPr-i)4 (6.37 mol) in benzene added to slurry of MgCl2 (3.15mol) in benzene; stirred at room temp. until dissolution of MgCl2 (24 h ); reflux for 1 h; evapd. (vac. 0.5 mm, room temp.); crystd. at -20°C (hexane/CH2Cl2= 2:1); elem. anal.;	91%

: 16940-66-2
sodium tetrahydroborate

: 7786-30-3
magnesium chloride

: magnesium borohydride

Conditions

Conditions	Yield
In diethyl ether ball milled and refluxed in Et2O;	90%
In neat (no solvent) (Ar); mechanical action (3 h, room temp.); extn. (Et2O);	76%
In not given

: potassium heptafluorotantalate

: 7786-30-3
magnesium chloride

: 7721-01-9
tantalum pentachloride

Conditions

Conditions	Yield
750 °C for 1 h in inert gas, molar ratio of K2TaF4:chloride = 1:2;	90%
700-1000 °C in inert gas, molar ratio of K2TaF7:chloride = 1:2;

Magnesium chloride Chemical Properties

Molecule structure of Magnesium chloride anhydrous (CAS NO.7786-30-3):

IUPAC Name: Magnesium dichloride
Molecular Weight: 95.211 g/mol
Molecular Formula: Cl₂Mg
Density: 2.32 g/mL at 25 °C(lit.)
Melting Point: 714 °C(lit.)
Boiling Point: 1412 °C
Refractive Index: n20/D 1.336
Storage Temp.: 2-8 °C
Water Solubility: 400 G/L (20 °C)
Sensitive: hygroscopic
H-Bond Acceptor: 2
Exact Mass: 93.922747
MonoIsotopic Mass: 93.922747
Heavy Atom Count: 3
Complexity: 2.8
Canonical SMILES: [Mg+2].[Cl-].[Cl-]
InChI: InChI=1S/2ClH.Mg/h2*1H;/q;;+2/p-2
InChIKey: TWRXJAOTZQYOKJ-UHFFFAOYSA-L
EINECS: 232-094-6
Product Categories: Inorganics;Crystal Grade Inorganics;Inorganic Salts;Magnesium Salts;MagnesiumMetal and Ceramic Science;Salts;Synthetic Reagents;G - M;Salt Solutions;Volumetric Solutions;PCR OptimizationMolecular Biology;PCR Reaction Components;PCR/Amplification;Optimization Reagents;BioUltraProtein Structural Analysis;DNA&RNA Purification;Molecular Biology;Molecular Biology Reagents;Optimization ReagentsMolecular Biology;Reagents;X-Ray Crystallography;BiochemicalsSynthetic Reagents;Magnesium;Companion Products and ReagentsSynthetic Reagents;Insect Platform;Serum-free Media

Magnesium chloride Uses

Magnesium chloride anhydrous (CAS NO.7786-30-3) is used for the manufacture of metal magnesium, disinfectants, fire extinguishing agents, frozen brine, ceramics and also used in flipper fabric, paper making, and in the manufacture of oxychloride cement, etc.

Magnesium chloride Production

In the Dow process, Magnesium chloride anhydrous is regenerated from magnesium hydroxide using hydrochloric acid:
Mg(OH)₂(s) + 2 HCl → MgCl₂(aq) + 2 H₂O(l)
It can also be prepared from magnesium carbonate by a similar reaction.

Magnesium chloride Toxicity Data With Reference

1.	mmo-omi 8000 ppm	APMBAY Applied Microbiology. 6 (1958),45.
2.	cyt-hmn:hla 2 mmol/L	JCLLAX Journal of Cellular Physiology. 78 (1971),217.
3.	dns-rat-ipr 2500 µmol/kg	JOENAK Journal of Endocrinology. 65 (1975),45.
4.	dni-rat:lvr 3300 µmol/L	BIJOAK Biochemical Journal. 146 (1975),697.
5.	oms-mus:ast 4 mmol/L	AMOKAG Acta Medicia Okayama. 33 (1979),141.
6.	orl-rat LD50:2800 mg/kg	JPETAB Journal of Pharmacology and Experimental Therapeutics. 35 (1929),1.
7.	ipr-rat LDLo:225 mg/kg	JPETAB Journal of Pharmacology and Experimental Therapeutics. 35 (1929),1.
8.	scu-rat LDLo:900 mg/kg	ENDOAO Endocrinology (Baltimore). 24 (1939),523.
9.	ipr-mus LD50:1338 mg/kg	COREAF Comptes Rendus Hebdomadaires des Seances de lAcademie des Sciences. 256 (1963),1043.
10.	ivn-mus LD50:14 mg/kg	TXAPA9 Toxicology and Applied Pharmacology. 22 (1972),150.
11.

Magnesium chloride Consensus Reports

Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Magnesium chloride Safety Profile

Hazard Codes: Irritant Xi
Risk Statements: 36/37/38-43-36/37
R36/37/38:Irritating to eyes, respiratory system and skin.
R43:May cause sensitization by skin contact.
R36/37:Irritating to eyes and respiratory system.
Safety Statements: 26-36-24/25-22-36/37-39
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
S24/25:Avoid contact with skin and eyes.
S22:Do not breathe dust.
S36/37:Wear suitable protective clothing and gloves.
S39:Wear eye / face protection.
WGK Germany: 1
RTECS: OM2800000
F: 3-10
Poison by intraperitoneal and intravenous routes. Moderately toxic by ingestion and subcutaneous routes. Human mutation data reported. In humid environments it causes steel to rust very rapidly. When heated to decomposition it emits toxic fumes of Cl⁻. See also MAGNESIUM.

Magnesium chloride Specification

Magnesium chloride anhydrous (CAS NO.7786-30-3) is also named as Aerotex Accelerator MX ; CCRIS 3961 ; Caswell No. 531 ; DUS-top ; EPA Pesticide Chemical Code 013902 ; HSDB 657 ; Magnesium chloride ; Magnesium chloride (Mg₂Cl₄) ; Magnesium chloride (MgCl₂) ; Magnogene ; NSC 529832 ; TMT 2 ; UNII-59XN63C8VM . Magnesium chloride anhydrous (CAS NO.7786-30-3) is colorless, odorless and a small piece, particle, block-type monoclinic crystal. Its various hydrates MgCl₂(H₂O)x. These salts are typical ionic halides, being highly soluble in water.

Product Name

Magnesium chloride

Synthetic route

Magnesium chloride Chemical Properties

Magnesium chloride Uses

Magnesium chloride Production

Magnesium chloride Toxicity Data With Reference

Magnesium chloride Consensus Reports

Magnesium chloride Safety Profile

Magnesium chloride Specification

Related Products

Hot Products